Volumetric Properties of Alkali Salt in Aqueous 1-Butyl-3-Methylimidazolium Tetrafluoroborate at Various Temperatures

Article Preview

Abstract:

Volumetric characterstics of multiple electrolytic solutions in a wide range of solute concentrations and solutions temperatutre are of fundamental importance for the understanding of numerous physicochemical processes occurring in various brances of the chemical industry as well as in the natural envirnoment. In a view of importance of NaCl as primary salts in seawater and most of other natural water, accurate thermophysical data is crucial for understanding industrial and natural processes [1]. Ionic interaction plays an important role in chemical reactions in solutions [2]. In fact, the effect of the addition of salts in aquous solutions of ILs is very complex, primarily because a large number of different types of intermolecular interactions come into play between the ion and water, ion and IL, and IL and water. From a thermodynamic perspective, the solvation of ionic species in the ILs is much more favored than in conventional solvents. This is one of the key advantages of using ILs in separations involving ionic species.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

659-663

Citation:

Online since:

January 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] I.M. Abdulagatov, N.D. Azizov, Densities and apparent molar volumes of concentrated aqueous LiCl solutions at high temperatures and high pressures, Chemical Geology. 230 (2006) 22–42.

DOI: 10.1016/j.chemgeo.2005.11.010

Google Scholar

[2] Y. Marcus, Ion Solvation. John Wiley & Sons publication, (1985).

Google Scholar

[3] I.M. Saaid, S.Q.A. Mahat, B. Lal, M.I.A. Mutalib, K.M. Sabil, Experimental investigation on the effectiveness of 1‑Butyl-3-methylimidazolium Perchlorate ionic liquid as a reducing agent for heavy oil upgrading, Industiral and Engneering Chemistry Research. 53 (2014).

DOI: 10.1021/ie500499j

Google Scholar

[4] B. Lal, M. Sahin, E. Ayranci, Volumetric studies to examine the interactions of imidazolium based ionic liquids with water by means of density and speed of sound measurements, J. Chem. Thermodyamics. 54 (2012) 142-147.

DOI: 10.1016/j.jct.2012.03.025

Google Scholar

[5] Y. Umebayashi, T. Yamaguchi, S. Fukuda, T. Mitsugi, M. Takeuchi, K. Fuji, S.I. Ishiguro, Raman spectroscopic study on alkaline metal ion solvation in 1-Butyl-3-methylimidazolium Bis(trifluoromethanesulfonyl) amide ionic liquid, Analytical Science. 24 (2008).

DOI: 10.2116/analsci.24.1297

Google Scholar

[6] N. Nishi, H. Murakami, S. Imakura, T. Kakiuchi, Facilitated transfer of alkali-metal cations by Dibenzo-18-crown-6 across the electrochemically polarized interface between an aqueous solution and a hydrophobic room-temperature ionic liquid, Analytical Chemistry. 78 (2006).

DOI: 10.1021/ac060797y

Google Scholar

[7] P. Wasserscheid, W. Keim, Ionic liquid new solution, for transition metal catalysis. Angewandte Chemie International Edition. 39 (2000) 3772-3789.

DOI: 10.1002/1521-3773(20001103)39:21<3772::aid-anie3772>3.0.co;2-5

Google Scholar

[8] R.L. Gardas, D.H. Dagade, S.S. Terdale, J.A.P. Coutinho, K.J. Patil, Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298. 15 K. J. Chem. Thermodyamics. 40 (2008) 695–701.

DOI: 10.1016/j.jct.2007.10.007

Google Scholar

[9] L.H. Oliveira, J.L. Silva, Jr., M. Aznar, Apparent and partial molar volumes at Iinfinite dilution and solid–liquid equilibria of Dibenzothiophene + alkane systems, J. Chem. Engineering Data. 56 (2011) 3955–3962.

DOI: 10.1021/je200327s

Google Scholar

[10] F.J. Millero, in: R.A. Horne (Ed. ), Structure and transport process in water and aqueous solutions, John Wiley, New York, 1972, p.519–564.

Google Scholar

[11] F. J Millero, D.H. Walter, Apparent molal volumes of aqueous monovalent salt solutions at various temperatures. J. Chem. Engineering Data. 13 (1968) 330–333.

DOI: 10.1021/je60038a009

Google Scholar

[12] A. Apelblat, E. Manzurola, Volumetric properties of aqueous solutions of lithium chloride at temperatures from 278. 15 K to 338. 15 K and molalities (0. 1, 0. 5, and 1. 0) mol·kg−1, J. Chem. Thermodynamics. 33 (2001) 1133–1155.

DOI: 10.1006/jcht.2001.0826

Google Scholar

[13] M. Sahin, E. Ayranci, Volumetric properties of (ascorbic acid + polyethylene glycol 3350 + water) systems at T = (288. 15, 298. 15, and 308. 15) K, J. Chem. Thermodynamics. 43 (2011) 177-185.

DOI: 10.1016/j.jct.2010.08.017

Google Scholar