Preparation and Photoactivity of Titanium Dioxide-Coated Carbon Felt Using Supercritical Carbon Dioxide

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Abstract:

TiO2–coated carbon felt (TCF) was prepared via a supercritical treatment with titanium tetraisopropoxide (TTIP) and different carbon felt as a precursor and support, respectively. The TCF samples with different carbon felts were characterized by X-ray diffraction, scanning electron microscopy, UV-VIS spectroscopy, particle size analyzer and BET surface area. The photocatalytic activities of samples were evaluated by congo red (CR) degradation. The result reveals that all the three samples show much higher photoactivity than the commercial P25. The activity order of the three samples is TCF1< TCF2 < TCF3. The photoactivity is strongly dependent on the surface area and the crystallite size: the larger the surface area and the smaller the crystallites, the higher the efficacy of photocatalytic degradation. The optimal photocatalytic condition is a CR concentration of 45 mg/l at pH 7.

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Advanced Materials Research (Volumes 146-147)

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1754-1760

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October 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Cordero, J.M. Chovelon, C. Duchamp, C. Ferronato and J. Matos: Appl. Catal. B: Environ. Vol. 73 (3) (2007), p.227.

Google Scholar

[2] S. Mozia, M. Toyoda, I. M. Nagaki, B. Tryba and A.W. Morawski: J. Hazardous Mater. Vol. 140 (1-2) (2007), p.369.

Google Scholar

[3] S. Fukahori, H. Ichiura, T. Kitaoka and H. Tanaka: Environ. Sci. Technol. Vol. 37(2003), p.1048.

Google Scholar

[4] H. Hou, H. Miyafuji and S. Saka:J. Mater. Sci. Vol. 41(24)(2006), p.8295.

Google Scholar

[5] S. Fukahori, H. Ichiura, T. Kitaoka and H. Tanaka: Appl. Cata. B: Environ. Vol. 46(3)(2003), p.453.

Google Scholar

[6] F.F. Li, Y.S. Jiang, M.S. Xia, M.M. Sun, B. Xue and X.H. Ren:J. Hazard. Mate. Vol. 165(1-3)(2009), p.1219.

Google Scholar

[7] T. Cordero, C. Duchamp, J.M. Chovelon, C. Ferronato and J. Matos: J. Photochem. Photobiol. A: Chem. Vol. 191(2-3) (2007), p.122.

Google Scholar

[8] A.K. Subramani, K. Byrappa, S. Ananda, K.M. Lokanatha, C. Ranganathaiah and M. Yoshimura: Bull. Mater. Sci. Vol. 30 (1) (2007), p.37.

DOI: 10.1007/s12034-007-0007-8

Google Scholar

[9] M. Dvoyashkin, R. Valiullin, J. Kärger and W.D. Einicke: J. Am. Chem. Soc. Vol. 2007(129), p.10344.

DOI: 10.1021/ja074101+

Google Scholar

[10] L. Ravichandran, K. Selvam, B. Krishnakumar and M. Swaminathan: J. Hazard. Mate. Vol. 167 (1-3) (2009), p.763.

Google Scholar

[11] V. Mangalampalli, S. Phanikrishna, D. Valluri and S. Machiraju: J. Hazard. Mate. Vol. 160 (2-3) (2008), p.568.

Google Scholar

[12] K. Romana and K. Tae-Jeong: J. Hazard. Mater. Vol. 163 (2-3) (2009), p.1179.

Google Scholar

[13] A. Jirapat, K. Puangrat and S. Supapan: J. Hazard. Mater. Vol. 168(1)(2009), p.253.

Google Scholar

[14] Z. Mengyue, C. Shifu and T. Yaowu: J. Chem. Technol. Biotechnol. Vol. 64 (1995), p.339.

Google Scholar

[15] M.S. Kim, K.M. Hong and J. G. Chung: Water Res. Vol. 37(14) (2003), p.3524.

Google Scholar