Mid-IR and Raman Spectral Properties of Geometrically Frustrated Atacamite Hydroxyl Copper Chloride

Abstract:

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The mid-IR and Raman spectra of geometrically frustrated atacamite hydroxyl copper chloride are measured by FTIR spectroscopy and HR800 Raman spectroscopy, respectively. The microscopic origins of bands within the functional group and the fingerprint regions are suggested by the known crystal structure parameters. Five distinct regions involved in hydroxyl stretching, overtones, hydroxyl deformation, Cu-O stretching, O–Cu–O symmetric stretching and O–Cu–O bending modes, pyramid-structure Cl≡Cu3 vibration modes, lattice modes, respectively.

Info:

Periodical:

Advanced Materials Research (Volumes 146-147)

Edited by:

Sihai Jiao, Zhengyi Jiang and Jinglong Bu

Pages:

972-975

DOI:

10.4028/www.scientific.net/AMR.146-147.972

Citation:

W. J. Tao et al., "Mid-IR and Raman Spectral Properties of Geometrically Frustrated Atacamite Hydroxyl Copper Chloride", Advanced Materials Research, Vols. 146-147, pp. 972-975, 2011

Online since:

October 2010

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$35.00

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