Synthesis and Electrochemical Performance of Li3V2(PO4)3 Cathode Materials by Microwave-Assisted Carbothermal Reduction Method

Bo Quan Jiang; Shu Fen Hu; Zhi Qiang Ye

doi:10.4028/www.scientific.net/AMR.156-157.1199

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 156-157Synthesis and Electrochemical Performance of...

Synthesis and Electrochemical Performance of Li₃V₂(PO₄)₃ Cathode Materials by Microwave-Assisted Carbothermal Reduction Method

Abstract:

The lithium vanadium phosphate (Li3V2(PO4)3) cathode materials were synthesized by microwave- assisted carbothermal reduction method. The effects of microwave heating time and Li/V molar ratio on the structure and electrochemical performance of the prepared samples were investigated. The results show that the perfect crystal growth and good electrochemical performance ( first charge / discharge specific capacity of 160.8 mAh•g-1/151.3 mAh•g-1 and discharge decay rate of 7.90% after 30 cycles ) of the Li3V2(PO4)3 were obtained under the optimal conditions of heating time 11 min and Li/V molar ratio 3.05:2.0. The voltage values appeared at the oxidation and reduction peaks of the cyclic voltammetry curves were proved to be basically consistent with those appeared at the charge / discharge curves. The lithium ion diffusion coefficient was determined to be 2.320 ×10-9 cm2•s-1 by electrochemical impedance spectroscopy and mathematical models derived from simulative equivalent circuit.

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Advanced Manufacturing Technology, ICAMMP 2010

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Advanced Materials Research (Volumes 156-157)

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1199-1202

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.156-157.1199

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Online since:

October 2010

Authors:

Bo Quan Jiang, Shu Fen Hu, Zhi Qiang Ye

Keywords:

Carbothermal Reduction, Cathode Material, Li₃V₂(PO₄)₃, Lithium-Ion Battery

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References

[1] Xiaodong Guo, Heng Liu, Deqiao Wu, Benhe Zhong. Materials Review Vol. 23 (2009), p.29.

Google Scholar

[2] M Y Saidi, J Barker, H Huang, J L Swoyer. J. Power Sources Vol. 119-121 (2003), p.266.

Google Scholar

[3] Shengkui Zhong, Jian Wang, Yanhong Li. New chemical materials Vol. 36 (2008), p.19.

Google Scholar

[4] Xuechou Zhou, Yongmei Liu, Yonglan Guo. Solid-State Communications Vol. 145(2008), p.261.

Google Scholar

[5] Linli Jiang, Yanwen Tian, Liying Liu. J. Materials and Metallurgy Vol. 5 (2006), p.115.

Google Scholar

[6] Lingqian Chen. Battery(in Cjinese) Vol. 37 (2007), p.107.

Google Scholar

[7] Quanqi Chen, Jianming Wang, Zhang Tang. Electrochimica Acta Vol. 52(2007), p.5251.

Google Scholar

[8] Shihui Xu . Chengdou, Sichuan University, China, 2006, p.97.

Google Scholar

[9] H Liu, H P Zhang, L J Fu, Y P Wu and H O Wu. J. Power Sources Vol. 159 (2006), p.717.

Google Scholar

[10] Suqin Liu, Shicai Li, Kelong Huang. ACTA CHIMICA SINICA Vol. 65(2007), p.10.

Google Scholar