Photo-Aging of Polyurethane Coating Based on TDI-TMP and N3390

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Abstract:

The photoaging of polyurethane coating based on TDI-TMP and N3390 was conducted though UV exposure. The properties of studied polyurethane coatings, such as film thickness loss, gloss loss, discoloration and ultraviolet absorbance were examined at some aging intervals. In addition, scanning electronic microscopy (SEM) and Fourier transform infra-red spectroscopy (FTIR) were used to measure the morphology and chemical change of coatings before and after exposed in a UV lamp chamber. It was found that the addition of N3390 had a significant effect on the discoloration of polyurethane coating, and coating without N3390 had greater degradation. The above results suggested that a mixed curing agent system with a mass ratio of TDI-TMP to N3390 between 5:5 and 3:7 be a possible substitute of pure N3390 for weather resistance PU coatings.

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Periodical:

Advanced Materials Research (Volumes 189-193)

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1100-1104

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February 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] Sanders H, Frish CK, in: Polyurethanes chemistry and technology, Part I. Chemistry. New York: Wiley, (1962).

Google Scholar

[2] Oertel G, in: Polyurethane handbook, New York: Macmillan Publishing Co., Inc., (1985).

Google Scholar

[3] C. Decker, F. Masson, R. Schwalm. Polym. Degrad. Stab. 83 (2004), p.309.

Google Scholar

[4] Small Wicks, Jones, Boba Si, in: Organic coatings science and technology, Chemical Industry Press, Beijing (In chinese), (2002).

Google Scholar

[5] R. P. Singh, Namrata S. Tomer, Veera Bhadraiah. Polym. Degrad. Stab. 73 (2001), p.443.

Google Scholar

[6] J E Pickett. Macromol. Symp., 115(1997), p.127.

Google Scholar

[7] Albert JG. Coatings & Linings, MP/September 1995, p.32.

Google Scholar

[8] Brennan P, Fedor C. Sunlight, UV and accelerated weathering. Presented at SPE Automotive RETEC, November (1987).

Google Scholar

[9] Grossman G. Coatings Technol, 49(633) (1977), p.45.

Google Scholar

[10] Osterhold M, Glǒckner P. Prog. Org. Coat. 41(2001), p.177.

Google Scholar

[11] B. W. Johnson, R. McIntyre. Prog. Org. Coat. 27 (1) (1996), p.95.

Google Scholar

[12] K. A. Wood. Prog. Org. Coat. 43 (1) (2001), p.207.

Google Scholar

[13] X. F. Yanga, C. Vangb, D.E. Tallmana, G.P. Bierwagenb, S.G. Croll, S. Rohlika, Polym. Degrad. Stab. 74 (2001), p.341.

Google Scholar