Flame Retardant Polyamide 6 Composites Using NMH or NMH/MCA/APP

Article Preview

Abstract:

In this paper, flame retardant Polyamide 6 (PA6) composites were prepared by nano-magnesium hydroxide (NMH) or its composites with melamine cyanurate(MCA) and ammonium polyphosphate(APP). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to analyze the structure of nano-magnesium hydroxide. The properties including tensile properties, molten index (MFI), rockwell hardness and density of flame retardant PA6 were analyzed. Orthogonal experiments were used to study flame retardancy of PA6 with NMH, MCA and APP. The results showed NMH had hexagonal orthorhombic crystal structure with size of 300×200×100nm. Density of polyamide 6 showed an upward trend when the content of NMH was increasing, the mechanical properties and hardness changed little while processing performance serious declined. The flame retardance of nitrogen-phosphorus -inorganic flame retardants was not desirable.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 189-193)

Pages:

1208-1211

Citation:

Online since:

February 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Weidong Wu, Charles Q. Yang. Comparison of different reactive organophosphorus flame retardant agents for cotton. Part II: Fabric flame resistant performance and physical properties [J]. Polymer Degradation and Stability. 2007, 92: 363-369.

DOI: 10.1016/j.polymdegradstab.2006.12.005

Google Scholar

[2] D.C.O. Marney , L.J. Russell , D.Y. Wu, T. Nguyen, et al. The suitability of halloysite nanotubes as a fire retardant for nylon 6 [J]. Polymer Degradation and Stability. 2008, 93: 1971-(1978).

DOI: 10.1016/j.polymdegradstab.2008.06.018

Google Scholar

[3] M. Modesti, A. Lorenzetti, S. Besco, et al. Synergism between flame retardant and modified layered silicate on thermal stability and fire behaviour of polyurethane nanocomposite foams [J]. Polymer Degradation and Stability. 2008, 93: 2166-2171.

DOI: 10.1016/j.polymdegradstab.2008.08.005

Google Scholar

[4] J. Zhang, J. Hereid, M. Hagen, et al. Effects of nanoclay and fire retardants on fire retardancy of a polymer blend of EVA and LDPE [J]. Fire Safety Journal. 2009, 44: 504-513.

DOI: 10.1016/j.firesaf.2008.10.005

Google Scholar

[5] M.A. Cardenas, D. Garc a-Lopez, I. Gobernado-Mitre, e tal. Mechanical and fire retardant properties of EVA/clay/ATH nanocomposites -Effect of particle size and surface treatment of ATH filler [J]. Polymer Degradation and Stability. 2008, 93: 2032-(2037).

DOI: 10.1016/j.polymdegradstab.2008.02.015

Google Scholar