Paper Titles

Study on the Composite Strengthening Effect of Talc and Kyanite Addition on Corundum–Mullite Based Ceramic Foam
p.429

Effect of Forming Pressure and Sintering Temperature on Thermal Expansion Property of Li₂O-Al₂O₃-P₂O₅-SiO₂ Glass-Ceramics
p.436

Influence of Thickness and Density of Nonwoven Sound-Absorbing Material on the Sound-Absorption Capability
p.440

Study of Manufacturing Battery-Grade Co₃O₄ of Sphere-Shape
p.444

Synthesis and Property of a New Photochromic Diarylethene Bearing Thiophene and a Six-Membered Aryl Unit
p.448

Synthesis, Photochromism and Application of a Novel Diarylethene Bearing a Thiazole Unit
p.452

Synthesis and Characterization of Multiferroic NiFe₂O₄/BiFeO₃ Nanocomposites by Modified Pechini Method
p.456

Research on Profile Shock-Cushioning Performance of Foamed Aluminum-Polyurethane Composite Material
p.460

Growth of Tl-2212 Films on CeO₂-Buffered Sapphire Substrates
p.466

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 197-198Synthesis and Property of a New Photochromic...

Synthesis and Property of a New Photochromic Diarylethene Bearing Thiophene and a Six-Membered Aryl Unit

Article Preview

Abstract:

A novel photochromic diarylethene based on thiophene and a six-membered aryl moieties 1-[(2-methyl-5-(p-methylphenyl)-3-thienyl)]-2-[(2-trifluoromethylphenyl)]perfluorocyclopentene(1a) has been synthesized. Its properties, including photochromic behavior and fluorescent properties, have been investigated. The results showed that this compound exhibited reversible photochromism, changing from colorless to purple after irradiation with UV light both in solution and in PMMA amorphous film. The fluorescence intensity decreased along with the increase of solution concentration. The diarylethene exhibited relatively strong fluorescence at different solvent.

You might also be interested in these eBooks

New and Advanced Materials

Info:

Periodical:

Advanced Materials Research (Volumes 197-198)

Pages:

448-451

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.197-198.448

Citation:

Cite this paper

Online since:

February 2011

Authors:

Hong Liang Liu, Shou Zhi Pu, Hui Li, Gang Liu

Keywords:

Diarylethene, Fluorescence, Photochromism, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Irie: Chem. Rev. Vol. 100 (2000), p.1685.

[2] S. Kawata: Chem. Rev. Vol. 100 (2000), p.1777.

[3] H. Tian and S.J. Yang: Chem. Soc. Rev. Vol. 33 (2004), p.85.

[4] M. Irie, T. Fukaminato, T. Sasaki, N. Tamai and T. Kawai: Nature Vol. 420 (2002), p.759.

DOI: 10.1038/420759a

[5] K. Matsuda and M. Irie : Chem. dEur. J. Vol. 7 (2001), p.3466.

[6] M. Morimoto, S. Kobatake, M. Irie: J. Am. Chem. Soc. Vol. 125 (2003), p.11080.

[7] K. Morimitsu, K. Shibata, S. Kobatake and M. Irie: J. Org. Chem. Vol. 67 (2002), p.4574.

[8] K. Matsuda and M. Irie : J. Photochem. Photobiol. C. Vol. 5 (2004), p.169.

[9] M. Irie: Chem. Rev. Vol. 100 (2000), p.1685.

[10] K. Higashiguchi, K. Matsuda, N. Tanifuji and M. Irie: J. Am. Chem. Soc. Vol. 127 (2005), p.8922.

[11] S.Z. Pu, M. Li and C.B. Fan, G. Liu and L. Shen: J. Mol. Struct. Vol. 919 (2009), p.100.

[12] M. Takeshita, M. Ogawa, M. Keisuke and T. Yamato: J. Phys. Org. Chem. Vol. 16 (2003) p.148.

[13] K. Uchida, S. Nakamura and M. Irie: Research on Chemical Intermediates Vol. 21 (1995) p.861.

[14] S.Z. Pu, C.B. Fan, W.J. Miao and G. Liu: Tetrahedron Vol. 64 (2008) p.9464.

[15] S.Z. Pu, H. Li, G. Liu and W.J. Liu: Tetrahedron Lett. Vol. 51 (2010), p.3575.

[16] S.Z. Pu, W.J. Miao S.Q. Cui, G. Liu and W.J. Liu: Dyes Pigm. Vol. 87 (2010), p.257.

[17] G. Li, T. Zheng, S. Z. Pu, and J. K. Xu: Acta Cryst. E. Vol. 62 (2006), p. o2877.

[18] Z.X. Li, L.Y. Liao,W. Sun, C.H. Xu, C. Zhang, C.J. Fang and C.H. Yan: J. Phys. Chem. C. Vol. 112 (2008), p.5190.

[19] S.Z. Pu,T.S. Yang, G.Z. Li, J.K. Xu and B. Chen: Tetrahedron Lett. Vol. 47 (2006), p.3167.

[20] S.Z. Pu, T.S. Yang, J.K. Xu and B. Chen: Tetrahedron Lett. Vol. 47 (2006), p.6473.