Effect of Trace RE on Corrosion Behavior of Ag-Cu-Ni Alloys

Article Preview

Abstract:

The corrosion performance of Ag-Cu-Ni-RE alloys in Na2S has been studied in order to assess the influence of rare earth (lanthanum and cerium) on the Ag-Cu-Ni alloys. Optical microscopy has been used to characterize the microstructures of the samples prior to the electrochemical tests. SEM, EDS and XRD have been used to observe the corrosion morphologies and chemical compositions of the samples. The electrochemical tests has been carried out at room temperature in 0.5, 1and 2% (wt. %) Na2S. The results reveal that the Ag-Cu-Ni-RE alloys exhibit improved corrosion resistance, as well as fine and uniform microstructures. Moreover, surface layers forming on Ag-Cu-Ni-RE alloys exhibit improved protective properties compared to the film growing on the Ag-Cu-Ni alloy. Here, it is also found that when comparing to the dilute Na2S solution conditions, there would be a little decrease of the corrosion rate in 2wt. %Na2S solution. In addition, Ag-Cu-Ni-La-Ce alloy generally exhibits the best corrosion resistance.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 197-198)

Pages:

507-513

Citation:

Online since:

February 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P.F. Warner, U.S. Patent 3, 498, 800. (1970).

Google Scholar

[2] T.D. Burleigh, C. Shi, S. Kilic, S. Kovacik, T. Thompson and R.M. Enick: Corrosion Vol. 58 (2002), p.49.

Google Scholar

[3] J.P. Franey and K. Donaldson: Tappi Journal (2001), p.381.

Google Scholar

[4] W. Kono, U.S. Patent 4, 775, 511. (1988).

Google Scholar

[5] S. Iwano, K. Nishimoto, R. Tamura and S. Takeuchi: Philosophical magazine Vol. 86(2006), p.435.

Google Scholar

[6] D.M. Herman, G.H. Cao, A.T. Becker and A.M. Russell: Journal of alloys and compounds Vol. 454(2008), p.292.

Google Scholar

[7] K.A. Gschneidner and F.W. Calderwood: Journal of Phase Equilibria Vol. 4(1983), p.364.

Google Scholar

[8] K. Wojtasik and S. Stolarz: Metal Powder Report Vol. 53(1998), p.41.

Google Scholar

[9] Fuxiang Huang, Min Li, Yonghong Xu, Ying Zhang and Ping Yin: перспективиые материалы Vol. 5 (2009), p.29.

Google Scholar

[10] Christopher M.A. Brett, Heloisa A. Acciari and Antonio C. Guastaldi: Key Engineering Materials Vols Vol. 230-232 (2002), p.463.

Google Scholar

[11] J.A. Dean: Lange's Handbook of Chemistry, section 6 of Thermodynamic Properties (McGraw-Hill 1999).

Google Scholar

[12] M.L. Santos, H.A. Acciari, L.C.O. Vercik and A.C. Guastaldi: Materials Letters Vol. 57 (2003), p.1888.

Google Scholar

[13] K. Nisancioglu, O. Lunder and T.R. Aune: 47th Annual World Magnesium Conference (Cannes, France 1990) p.43.

Google Scholar

[14] Lynn A. O'Brien and R.M. German: Journal of materials science Vol. 23 (1988), p.3563.

Google Scholar