Synthesis, Fluorescence Properties of 2-Acetyl-2'-Chloroacetanilide with Rare Earth Nitrates Complexes

Abstract:

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The reaction of 2-acetyl-2'-chloroacetanilide (L) with rare earth nitrates in CH3CH2OH followed by recrystallization in CH3CH2OH gave rise to colorless block crystals materials. The complexes and ligand were analyzed by FAB, elemental analysis(C, H, N), FT-IR spectra, TG-DTA, molar conductivity and X-ray single crystal diffraction. The fluorescence properties of ligand and the Eu (Ⅲ) complex also have been investigated. The results of crystal structure and spectral data show that the rare earth ions coordinated with oxygen and nitrogen atoms of the ligand, the nitrate and coordinated water molecules. The Eu (Ⅲ) complex material shows characteristic red emissions.

Info:

Periodical:

Advanced Materials Research (Volumes 219-220)

Edited by:

Helen Zhang, Gang Shen and David Jin

Pages:

574-577

DOI:

10.4028/www.scientific.net/AMR.219-220.574

Citation:

X. S. Tai and L. T. Wang, "Synthesis, Fluorescence Properties of 2-Acetyl-2'-Chloroacetanilide with Rare Earth Nitrates Complexes", Advanced Materials Research, Vols. 219-220, pp. 574-577, 2011

Online since:

March 2011

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$35.00

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