Degradation Behaviour and Kinetics of UV Cured Epoxidised Soybean Oil Derivatives

Abstract:

Green resins based from sustainable resources are a requirement nowadays to replace non environmental coatings. Low (VOC) content epoxy which competes with conventional well established coating and high price could be derived from oil. UV curable resin is typically low VOC systems and offer advantages of rapid ambient cross linking and more energy efficient. Epoxy resins must have fast curing and low shrinkage upon cure which will give advantages to devices performance but epoxy resins are expensive and hence renewable resources from vegetable or non food oil can be used as raw materials.

• Periodical: Advanced Materials Research (Volumes 230-232)
• Pages: 94-98
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.230-232.94
• Online since: May 2011
• Authors: Mohammad Rahmah, Syuhaimi Ab.Rahman Mohammad, Mohamed Shaktur Khaled, Nawi Norwimie, Faiza Mohd Ahmad
• Keywords: Activation Energy, Degradation, Epoxidized Oil, Green Resin, Kinetic, Photoinitiator, UV-Curable

References

[1] C.A. Gracia-Fern´andez, S. G´omez-Barreiro, S. Ru´ız-Salvador, R. Blaine, Study of the degradation of a thermoset system using TGA and modulated TGA, Progress in Organic Coatings 54, p.332, (2005).

DOI: 10.1016/j.porgcoat.2005.08.002

[2] Biermann,U.,W. Friedt,S. Lang,W. Luhs,G. Machmuller J.O. Metzger M.R. Klass H.J. Schafer, and M.P. Schneider, New synthesis with oils and Fats as Renewable Raw Materials for the Chemical Industry, Angew. Chem. Int. Ed. Engl. 39, pp.2206-2224, (2000).

DOI: 10.1002/1521-3773(20000703)39:13<2206::aid-anie2206>3.0.co;2-p

[3] Pim-pahn Meyer, Niwat Techaphattana. Salamah Manundawee, Sasitorn Sangkeaw, Wannapit Junlakan, Chakrit Tongurai, Epoxidation of Soybean Oil and Jathropha Oil, Thammasat Int. J. Sc. Tech., Vol 13 Special edition, November (2008).

[4] Johannes T.P. Derksen,F. Petrus Cuperus, Peter Kolster, Paints and coatings from renewable resources, Industrial Crops and Products 3, pp.225-236, (1995).

DOI: 10.1016/0926-6690(94)00039-2

[5] F. Benard, B . Mailhot, J. Mallegol, J. LGardette, Photoageing of an electron beam cured polyurethane acrylate resin, Polymer degradation and thermal stability 93, pp.1122-1130, (2008).

DOI: 10.1016/j.polymdegradstab.2008.03.008

[6] Soo Jin Park, Fan-Long Jin, Jae-Rock Lee, Thermal and Mechanical properties of tetrafunctional epoxy resin toughened with epoxidised soybean oil, Materials Sciences and engineering A 374, pp.109-114, (2004).

DOI: 10.1016/j.msea.2004.01.002

[7] L. Barral, F. J. Diez, S. Garcia Garabal, J. Lopez, B. Montero, R. Montes, C. Ra mirez, M. Rico, Thermodegradation kinetic of a hybrid inorganic-organic epoxy system, European Polymer Journal 41, pp.1662-1666, (2005).

DOI: 10.1016/j.eurpolymj.2005.01.021

[8] Official methods and recommended Practices of the American Oil Chemists' Society, 3rd edn., American Oil Chemists'Society Campaign, (1980).

[9] S. Ma, J.O. Hill, S. Heng, A kinetic analysis of the pyrolysis of some australian coals bynon-isothermal thermogravimetry, J. Therm. Anal. 37, p.1161, (1991).

DOI: 10.1007/bf01913852

[10] H.E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Anal. Chem. 29, p.1702–1706 , (1957).

DOI: 10.1021/ac60131a045