Synthesis of 2-Nitrobenzaldehyde in the Presence of Ionic Liquids

Article Preview

Abstract:

A method for synthesizing of 2-nitrobenzaldehyde from 2-nitrobenzyl alcohol using ionic liquids (ILs) has been developed. The conversion of 2-nitrobenzyl alcohol and the selectivity of 2-nitrobenzaldehyde in the ionic liquids are higher than those in the traditional dichlorethane solvent. In addition, a reaction mechanism for the oxidation of 2-nitrobenzyl alcohol to 2-nitrobenzaldehyde is proposed.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Pages:

1146-1151

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. J. Lozar, A. J. Savall: Ind. Eng. Chem. Res. Vol. 34 (1995), p.3149

Google Scholar

[2] W. Davey, J. R. Gwilt: J. Chem. Soc. (Jan) (1950), p.204.

Google Scholar

[3] G.A. Artamkina, A.A. Grinfeld, I. P. Beletskaya: Tetrahedron Lett. Vol. 25 (1984), p.4989

Google Scholar

[4] B. Grob, R. Riesen: Chemische Industrie. Vol. 9 (1986), p.782

Google Scholar

[5] C. I. Sainz-Díaz: Monatshefte für Chemie. Vol. 133 (2002), p.9

Google Scholar

[6] J. Dupont, R. F. de Souza, P. A. Z. Suarez: Chem. Rev. Vol. 102 (2002), p.3667

Google Scholar

[7] M. Kosmulski, J. Gustafsson, J. B. Rosenholm: Thermochim. Acta. Vol. 412 (2004), p.47

Google Scholar

[8] H. Matsumoto, M. Yanagida, K. Tanimoto, M. Nomura, Y. Kitagawa, Y. Miyazaki: Chem. Lett. Vol. 29 (2000), p.922

Google Scholar

[9] A. Bosmann, L. Datsevich, A. Jess, A. Lauter, C. Schmitz, P. Wasserscheid: Chem. Commun. (2001), p.2494

DOI: 10.1039/b108411a

Google Scholar

[10] H. Hagiwara, Y. Sugawara, K. Isobe,; H. Takashi; T. Suzuki: Org. Lett. Vol. 6 (2004), p.2325

Google Scholar

[11] M. Galinski, A. Lewandowski, I. Stepniak: Electrochim. Acta. Vol. 51 (2006), p.5567

Google Scholar

[12] C. J. Adams, M. J. Earle, G. Roberts, K. R. Seddon: Commun. (1998), p. (2097)

Google Scholar

[13] A. Chrobok: Tetrahedron. Vol. 66 (2010), p.6212.

Google Scholar

[14] F. J. Hernández-Fernández, A. P. de los Ríos, L. J. Lozano-Blanco, C. Godínez: J Chem Technol Biotechnol. (2010-online)

Google Scholar

[15] J. G. Huddleston, A. E. Visser, W. M. Reichert, H. D. Willauer, G. A. Broker, R. D. Rogers: Green Chem. Vol. 3 (2001), p.156

Google Scholar