Effect of the Co-Substitution of Ca2+ and Si4+ on the Structure and Luminescence Properties of Y3Al5O12: Ce3+

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A series of phosphors with the composition of Y2.95-xCaxAl5-xSixO12: Ce3+0.05 (x=0, 0.15, 0.30, 0.45, 0.60, 0.75) were synthesized with conventional solid state reactions. The results of XRD patterns show that in a certain extent, the co-substitution of Ca2+ and Si4+ does not change the garnet structure of samples, while results in the shrink of crystal lattice(The cell parameter of phosphors decreases with the increment of co-substitution content monotonically. The former is in linear with the latter). The measurement of the excitation and emission spectra shows that the co-substitution of Ca2+ and Si4+ make the emission peak move to short wavelength. The amount of blue shift is also in linear with the co-substitution content.

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Edited by:

Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He

Pages:

1844-1849

DOI:

10.4028/www.scientific.net/AMR.233-235.1844

Citation:

Z. F. Mu et al., "Effect of the Co-Substitution of Ca2+ and Si4+ on the Structure and Luminescence Properties of Y3Al5O12: Ce3+", Advanced Materials Research, Vols. 233-235, pp. 1844-1849, 2011

Online since:

May 2011

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$35.00

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