Study on Gas-Phase Catalytic Conversion of Turpentine-Based Dipentene (TBDP) by Pd/C Catalysts

Abstract:

Turpentine-based dipentene (TBDP) contains limonene 30.32 %, terpinolene 31.35 %, α-terpinene 7.55 %, γ-terpinene 6.40 % and p-cymene 12.87 %. Three Pd/C catalysts were characterized by BET, XRD, TG-DTG and atomic absorption spectrometry (AAS). The properties of the catalysts on TBDP conversion were compared. Difference of catalytic competitive reactions of TBDP by catalyst A with the change of reaction temperature was discussed in detail. The yield of p-cymene at 280-310°C was over 95.0 %. It was important to control the reaction temperature for TBDP dehydrogenation catalyzed by Pd/C catalysts. It is valuable to probe the catalytic behaviors of Pd/C catalyst on TBDP dehydrogenation for research and development of efficient preparation technology of p-cymene from TBDP.

• Periodical: Advanced Materials Research (Volumes 236-238)
• Pages: 27-34
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.236-238.27
• Online since: May 2011
• Authors: Liang Wu Bi, Qiu Ge Zhang, Peng Wang, Zhen Dong Zhao, Da Wei Li, Yu Xiang Chen, Dong Mei Li, Yan Gu, Jing Wang, Xian Zhang Liu
• Keywords: Conversion Regularity, Gas-Phase Catalysis, p-Cymene, Pd/C Catalyst, Turpentine-Based Dipentene (TBDP)

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