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Determination of Prednisone Acetate at Trace Level by Flow Injection Analysis with Tris(1,10-Phenanthroline) Ruthenium(II) Chemiluminescence Detection

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Abstract:

A simple, sensitive and rapid method for flow injection with chemiluminescence analysis has been developed for the determination of prednisone acetate at trace level. This method is based on the luminescent properties of the tris(1,10-phenanthroline) ruthenium(II)-potassium permanganate -prednisone acetate in acidic medium sensitized by Na2SO3. The optimized experimental conditions are evaluated. Under the optimum experimental conditions, the linear ranges of prednisone acetate are: 4.0×10-10~4.0×10-8 g·mL-1 and 4.0×10-8~2.0×10-7 g·mL-1 with a low detection limit is 4.5×10-11 g·mL-1 and the relative standard deviation for 1.0×10-8 g·mL-1 sample is 1.04% (n=11). The proposed method has been successfully applied to the determination of prednisone acetate in tablets.

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Periodical:

Advanced Materials Research (Volumes 236-238)

Pages:

2729-2732

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.236-238.2729

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Online since:

May 2011

Authors:

Pi Xue Gong, Wei Hua Liu, Wen Wen Liu, Kang Du, Kang Liu, Wei Cao

Keywords:

Chemiluminescence, Flow Injection, Potassium Permanganate, Prednisone Acetate, Ruthenium (II)

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] M. H. Cheng, W. Y. Huang, A. I. Lipsey. Clin. Chem., (1988), 1897-1899

Google Scholar

[2] M. R. M. Santoro, E. B. Govato, E. R. M. Hackmann. Anal. Lett.. Vol. 26 (1993), 925-935

Google Scholar

[3] H. Hirata, T. Kasama, Y. Sawai, et al. J. Chromatogr. B.. Vol. 658 (1994), 55-61

Google Scholar

[4] Y. Iglesias, C. Fente, et al, Anal. Chim. Acta, Vol. 468 (2002), 43-52

Google Scholar

[5] Y. Iglesias, C. Fente, et al, Analyst, Vol. 125 (2000), 2071-2074

Google Scholar

[6] L. J. Owen, S. G. Keevil, Ann. Clin. Biochem., Vol. 42 (2005), 105-111

Google Scholar

[7] F. W. Wu, Z. K. He, Journal of Instrumental Analysis, Vol.19 (2000), 81-88

Google Scholar

[8] L. Mark, O. F. Sayo, Anal. Chem., Vol. 80 (2008), 4551-4574

Google Scholar

[9] Y. X. Li, C. Q., Zhu, L. Wang, Microchim. Acta. Vol. 150 (2005), 95-99

Google Scholar

[10] P. Yang, Y. H. Chen, Q. Y. Zhu, Microchim. Acta. Vol. 163 (2008), 263-269

Google Scholar

[11] Bree A. Gorman, Neil W. Barnett, Richard Bos., Anal. Chim. Acta. Vol. 541 (2005), 119-124

Google Scholar

[12] W. Cao, Y. J. Fu, P. X. Gong, et.al, Microchim. Acta, Vol. 168 (2010), 17-21

Google Scholar

[13] N. W. Barnett, B. J. Hindson, S. W. Lewis, et al, Anal. Chim. Acta. Vol. 421 (2000), 1-6

Google Scholar

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