Microstructural Characteristics of Toluene Insolubles from Coal Tar

Article Preview

Abstract:

Toluene insolubles (TI) in coal tar is harmful to the downstream hydrotreating, and it may be difficult to be removed by conventional filtration. The TI is separated from coal tar which is washed by toluene and centrifugated at 2000 rpm and analyzed by Fourier transform infrared (FTIR) spectra, scanning electron microscopy (SEM), particle size measurements, X-ray Diffraction analyses (XRD) and elemental analysis. It is concluded that TI in coal tar is present typically as globular aggregates. The primary particles range in size from less than 0.5μm to about 20μm. Characterization of TI in the coal tar showed that it is a nitrogen and oxygen rich material. TI is mainly inorganic elements representative of quartz, albite and calcite associated with kerogen material.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 236-238)

Pages:

637-640

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R. F. Xu: Clean Coal Technol Vol. 14 (2008), p.62

Google Scholar

[2] R. Hu, B. Li and X. C. Zhang: China Coal Vol. 5 (2008), p.69

Google Scholar

[3] J. Yan, C. S. Lv, A. H. Liu and J. W. Da: Petrochem. Technol. Vol.35 (2006), p.33

Google Scholar

[4] X. Z. Tian: Ind. Safety and Environ. Protect. Vol. 33 (2007), p.56

Google Scholar

[5] Z. W. Li: Chem. Engineer Vol. 23 (2009), p.57

Google Scholar

[6] D. Lin-Vien, N. B.Colthup, W. G. Fateley, and J. G. Grasselli: in The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press Publishers, Boston, MA (1991)

DOI: 10.1016/b978-0-08-057116-4.50005-5

Google Scholar

[7] B. Durand: in Kerogen: Insoluble Organic Matter from Sedimentary Rocks; Editions Technip: Paris, France (1980)

Google Scholar

[8] Z. Xu, Z. Wang, J. Kung, J. R. Woods, K. H. Chung, L. S. Kotlyar, B. D. Sparks and X. A. Wu: Fuel Vol. 84 (2005), p.661

Google Scholar

[9] F. Bensebaa, L. S. Kotlyar, B. D. Sparks and K. H. Chung: The Can. J. of Chem. Eng. Vol. 78 (2000), p.610

Google Scholar

[10] S. T. Tong: Fuel & Chem. Proc. Vol. 36 (2005), p.32

Google Scholar

[11] J. D. Miller, M. Misra: Fuel Proc. Technol. Vol. 6 (1982), p.27

Google Scholar