Synthesis of Misfit-Layered Copper-Manganese Oxides

Chen Liang Zhou; Qian Zhang; Shu Yun Xu; Ke Duan Zhi; Run Xia He; Quan Sheng Liu

doi:10.4028/www.scientific.net/AMR.239-242.1717

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 239-242Synthesis of Misfit-Layered Copper-Manganese...

Synthesis of Misfit-Layered Copper-Manganese Oxides

Abstract:

The misfit-layered copper-manganese oxides(CMO) was successfully synthesized by inserting Cu(OH)_X^Y+ into Buserite under hydrothermal conditions and characterized by X-ray diffraction, AAS, SEM, TEM and BET. The single misfit-layered CMO can be obtained when Cu/Mn mole ratio is 0.67. SEM and HRTEM reveal that the as-synthesized material is a sheet-like crystal and the interlayer distance corresponding to the spacing of [MnO₆] and [Cu(OH)_X^Y+] is 0.47nm.

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Periodical:

Advanced Materials Research (Volumes 239-242)

Pages:

1717-1720

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.239-242.1717

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Online since:

May 2011

Authors:

Chen Liang Zhou, Qian Zhang, Shu Yun Xu, Ke Duan Zhi, Run Xia He, Quan Sheng Liu

Keywords:

Buserite, Copper-Manganese Oxide, Misfit-Layered Structure

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