Study on the Chemical Modification of Titanium-Doped Silicone Using Hydroxyl-Terminated Saturated Polyester

Zhi Feng Hao; Xue Mei Wang; Hong Xia Hou; Ya Hong Wu; Hua Gong Li; Jian Yu

doi:10.4028/www.scientific.net/AMR.239-242.2817

Paper Titles

Influence of the Pore Structure on the Reaction Characteristics of the Gas Sensitive Porous Medium
p.2799

Only Formation of ZrAl₃ Phase Obtained by Self-Propagating Reaction from Zr-Al Elemental Powders
p.2805

Experimental Study on the Crystallinity and Mechanical Properties of the Injection Molded Polypropylene
p.2809

Nitroso-R-Salt in Aqueous Solutions for Redox Flow Battery Application
p.2813

Study on the Chemical Modification of Titanium-Doped Silicone Using Hydroxyl-Terminated Saturated Polyester
p.2817

Research on Salt Fog Corrosion Behavior of Welded Joint of 7N01-T4 Aluminum Alloy for High-Speed Train
p.2822

Effect of KCl on Crystal Morphology of Electrodepisited Cu₂O Thin Films
p.2827

Tetra-(N-Phenylpyrazole)-Porphyrin/β-Cyclodextrin Incorporated CNT Film Modified Hemoglobin Sensor
p.2831

Annealing Effects on Structural and Magnetic Properties of Al doped ZnO Thin Films
p.2835

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 239-242Study on the Chemical Modification of...

Study on the Chemical Modification of Titanium-Doped Silicone Using Hydroxyl-Terminated Saturated Polyester

Abstract:

In this paper, a kind of titanium-doped silicone prepolymer(TDS) was modified by hydroxyl-terminated saturated polyester (HTSP) by condensation polymerization. By Fourier Transform Infrared Spectroscopy (FTIR) the reaction of ethoxy groups of the TDS prepolymer with hydroxyl groups of the HTSP during condensation polymerization process was conﬁrmed. The resins were cured with blocked polymeric isocyanate. The inﬂuence of the HTSP content on the properties of the modified resins such as thermal stability, corrosion resistance, as well as mechanical and other properties, were discussed in detail. The results showed that the properties of the resins were improved greatly after modification, and the optimal mass ratio of TDS to HTSP in the modified resins was 1:1. Thermogravimetry analysis (TGA) studies indicated that the weight loss of this sample（wTDS : wHTSP =1:1） was not obviously below 400°Cand the impedance value of this coating was significantly higher than that of the others.