Synthesis and Characterization of Ni(OH)2/Multiwalled Carbon Nanotubes Nanocomposites for Electrochemical Capacitors

Article Preview

Abstract:

Ni(OH)2/multiwalled carbon nanotubes (Ni(OH)2/MWNTs) nanocomposites were synthesized by hydrothermal method. The microstructures of such nanocomposites were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Electrochemical properties studies were carried out using cyclic voltammetry (CV), galvanostaitc charge/discharge and electrochemical impedance spectroscopy method. The presence of MWNTs network in the Ni(OH)2 significantly improved the electrical conductivity of the host Ni(OH)2 by the fromation of conducting network of MWNT and the active sites for the redox rection of the metal hydroxide. The specific capacitance of the new composites was significantly improved (MWNTs of 20 wt.%, 2144 F/g) compared to Ni(OH)2 (MWNTs of 0 wt.%, 1772 F/g) in 6 M KOH solution at a charge-discharge current density of 4 mA/cm2. Therefore, the Ni(OH)2/MWNTs nanocomposites can be a potential application electrode material for electrochemical capacitors.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 239-242)

Pages:

2968-2971

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J.H. Jang, S.J. Han, T.W. Hyon and S.M. Oh: J. Power Sources Vol. 123 (2003), p.79

Google Scholar

[2] B.E. Conway: J. Electrochem. Soc. Vol. 138 (1991), p.1539

Google Scholar

[3] S. Sarangapani, B.V. Tilak and C.P. Chen: J. Electrochem. Soc. Vol. 143 (1996), p.3791

Google Scholar

[4] D. Qu and H. Shi: J. Power Sources Vol. 74 (1998), p.99

Google Scholar

[5] E. Frackowiak and F. Beguin: Carbon Vol. 39 (2001), p.937

Google Scholar

[6] B. E. Conway: Electrochemical Supercapacitors (Plenum Press, New York 1999)

Google Scholar

[7] C. Niu, E.K. Sichel, R. Hoch, D. Moy and H. Tennent: Appl. Phys. Lett. Vol. 70 (1997), p.1480

Google Scholar

[8] R.Z. Ma, J. Liang, B.Q. Wei, B. Zhang, C.L. Xu and D.H. Wu: J. Power Sources Vol. 84 (1999), p.126

Google Scholar

[9] K.H. An, W.S. Kim, Y.S. Park, Y.C. Choi, S.M. Lee, D.C. Chung, D.J. Bae, S.C. Lim and Y.H. Lee: Adv. Mater. Vol. 13 (2001), p.497

Google Scholar

[10] G. Arabale, D. Wagh, M. Kulkarni, I.S. Mulla, S.P. Vernekar, K. Vijayamohanan and A.M. Rao: Chem. Phys. Lett. Vol. 376 (2003), p.207

DOI: 10.1016/s0009-2614(03)00946-1

Google Scholar

[11] R. Jenkins and R.L. Snyder: Introduction to X-ray Powder Diffractometry (John Wiley & Sons, New York 1996)

Google Scholar