Synthesis and Crystal Structure of a Novel Copper Complex Cu(Phen)(C8H7O2) 2

Abstract:

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Reactions of a freshly prepared Cu(OH)2×yH2O precipitate, 2-methyl benzoic acid with 1,10’-phenanthroline in C2H5OH/H2O afforded Cu(phen)(C8H7O2)2. The title compound was structurally characterized by X-ray diffraction methods. The unit of complex molecule was proposed 4+2 coordination sphere. In the crystal, molecules are connected by aryl π-π packing forming chains along [010] direction, the supramolecular double chains are further constructed two-dimension layers which parallel to (011) by π-π packing interactions.

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Periodical:

Edited by:

Fei Hu and Beibei Wang

Pages:

132-135

DOI:

10.4028/www.scientific.net/AMR.279.132

Citation:

P. Xia "Synthesis and Crystal Structure of a Novel Copper Complex Cu(Phen)(C8H7O2) 2", Advanced Materials Research, Vol. 279, pp. 132-135, 2011

Online since:

July 2011

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$35.00

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