Enhanced Photocatalytic Activity of TiO2 by (Tetracarboxyphthalocyaninatio) Cobalt (II)

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(Tetracarboxyphthalocyaninato) cobalt (Ⅱ) was used as dye to enhance the photocatalytic activity of nano-TiO2 in visible light. The photocatalyzer was prepared by phthlocyanine Co and TiO2, which was called TPC. The photocatalytic process of removal of benzene was investigated in visible light and ultraviolet. Results reveal that TPC can enhance photocatalytic activity of TiO2. The Benzene removal of TPC catalyst at 4.5 h was 52.80 % in incandescent lamp, at the same time it was 41.86% higher than nano-TiO2. The Benzene removal of TPC catalyst at 4.5 h was 43.53% in fluorescent lamp, at then 28.03% higher than nano-TiO2. The Benzene removal of TPC catalyst at 4.5 h was 36.58% under ultraviolet, at then 5.50% lower than nano-TiO2. The Benzene removal of TPC catalyst at 4.5 h was 10.69% in incandescent lamp, at then 2.15% higher than nano-TiO2. TPC catalyst should enhance ability of liquid photocatalytic oxidation TiO2. The highest photocatalytic degradation of nitrobenzene and methylene blue were separately 76.60 % and 21.02 % under incandescent light.

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Advanced Materials Research (Volumes 295-297)

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1433-1435

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July 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Fujishima, K. Honda. Nature. Vol. 37 (1972), p.238.

Google Scholar

[2] Zou Z, Ye J, Sayama K, Arakawa H. Nature. Vol. 414 (2001), pp.625-627.

Google Scholar

[3] Xiaorui Song, Xueson Wang, Baowen Zhang. Progress in Chemistry. Vol. 20 No.10 (2008), pp.1524-1533.

Google Scholar

[4] Jingbo Zhang, Arie Zaban. Electrochimica Acta. Vol. 53 (2008), pp.5670-5674.

Google Scholar

[5] Gratzel M. J Photochem Photobiol C: Photochem Rev. Vol. 4 (2003), pp.145-153.

Google Scholar

[6] Victor N. Nemykin, Ann E. Polshyna, Svetlana A. Borisenkova, et al. Journal of Molecular Catalysis A: Chemical. Vol. 264, (2007), pp.103-109.

Google Scholar

[7] Yantao Qin, Min Wu , Junjie Zhang, et al. Journal of Material s Science & Engineering. Vol. 26, No. 2 (2008), pp.220-222.

Google Scholar

[8] Yanmin Wang, Maofeng Zhang, Tingxi Li, et al. New Chemical Materials. Vol. 35, No. 8 (2007), pp.71-79.

Google Scholar

[9] Yongqian Xu, Shiguo Sun, Xiaojun Peng. Chemistry Bulletin. Vol. 69 (2006), p.350.

Google Scholar

[10] Fattima Al-Zahra G. Gassim, Ahmed N. Alkhateeb, Falah H. Desalination. Vol. 209 (2007), pp.342-349.

Google Scholar

[11] K. Rajeshwara, M. Osugib, W. Chanmaneec, et al. Photochemistry Reviews. Vol. 9 (2008), pp.171-192.

Google Scholar

[12] J. Nieto, J. Freer, D. Contreras, et al. Journal of Hazardous Materials. Vol. 155 (2008), pp.45-50.

Google Scholar

[13] Chen Huang, Soo Wohn Lee, Tae Ho Kima, et al. Journal of the European Ceramic Society. Vol. 26 (2006), pp.2231-2239.

Google Scholar