Effects of Conductive Supports on the Growth and Capacitive Performance of Nanostructured Manganese Oxides

Article Preview

Abstract:

The manganese oxide (MnO2) nanocrystals were formed on the surface of graphene oxides (GOs) and multi−walled carbon nanotubes (MWCNTs) through a facial hydrothermal route, respectively. It is found that the similar flower−like MnO2 nanocrystals covered on both conductive supports. Moreover, more dense and less size of MnO2 nanocrystals appeared on the surface of MWCNTs, whereas more perfect crystal structures for MnO2/GOs. Electrochemical measurements showed that both the nanocomposite electrodes exhibited nearly ideal capacitive behavior, and large capacitive value can be obtained for MnO2/GOs, while high stability for MnO2/MWCNTs. The high capacitance performance arises from the unique nanostructure of the nanocrystals, which facilitate the contact of the electrolyte and the active materials, and carbon−based materials provide an effective support for the formation of the nanocrystals and conductive pathway for the nanocomposite electrodes.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 306-307)

Pages:

1153-1156

Citation:

Online since:

August 2011

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Toupin, T. Brousse and D. Belanger: Chem. Mater. 16 (2004) 3184−3190.

Google Scholar

[2] R. R. Jiang, T. Huang, Y. Tang, J. L. Liu, L. G. Xue, J. H. Zhuang and A. S. Yu: Electrochim. Acta 54 (2009) 7173−7179.

Google Scholar

[3] J. Yan, Z. G. Fan, T. Wei, W. Z. Qian, M. L. Zhang and F. Wei: Carbon 48 (2010) 3825−3823.

Google Scholar

[4] Y. J. Yang, E. H. Liu, L. M. Li, Z. Z. Huang, H. J. Shen, X. X. Xiang: J. Alloys Compd. 487 (2009) 564−567.

Google Scholar

[5] J. M. Ko and K. M. Kim: Mater. Chem. Phys. 114 (2009) 837−841.

Google Scholar

[6] S. Chen, J. W. Zhu, X. D. Wu, Q. F. Han, and X. Wang: ACS NANO 4 (2010) 2822−2830.

Google Scholar

[7] W. S. Hummers and R. E. Offeman: J. Am. Chem. Soc. 80 (1958) 1339−1339.

Google Scholar