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Effects of Conductive Supports on the Growth and Capacitive Performance of Nanostructured Manganese Oxides
Abstract:
The manganese oxide (MnO2) nanocrystals were formed on the surface of graphene oxides (GOs) and multi−walled carbon nanotubes (MWCNTs) through a facial hydrothermal route, respectively. It is found that the similar flower−like MnO2 nanocrystals covered on both conductive supports. Moreover, more dense and less size of MnO2 nanocrystals appeared on the surface of MWCNTs, whereas more perfect crystal structures for MnO2/GOs. Electrochemical measurements showed that both the nanocomposite electrodes exhibited nearly ideal capacitive behavior, and large capacitive value can be obtained for MnO2/GOs, while high stability for MnO2/MWCNTs. The high capacitance performance arises from the unique nanostructure of the nanocrystals, which facilitate the contact of the electrolyte and the active materials, and carbon−based materials provide an effective support for the formation of the nanocrystals and conductive pathway for the nanocomposite electrodes.
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1153-1156
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August 2011
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© 2011 Trans Tech Publications Ltd. All Rights Reserved
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