Preparation of TbBO3 Powder and Growth of TbBO3 Crystal

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Abstract:

Triclinic and hexagonal structure of TbBO3 was synthesized by Sol-Gel combustion method and high temperature solid state method respectively. The TbBO3 crystal was grown by fluxing Czochralski(CZ) method and LiBO2 as flux. The crystal structure was studied by FT-IR and DTA. The results of powder magnetic susceptibility of hexagonal one showed that TbBO3 may be a good candidate magneto optical material.

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Advanced Materials Research (Volumes 306-307)

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416-422

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August 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.Q. Liu, Z.Q. Le, D.F. Shen, Magnetooptics, first ed., Shanghai scientific and technical publishers, Shanghai, (2001).

Google Scholar

[2] Z.J. Wang, Z.P. Yang, P. L. Li, Luminescence characteristics of LiCaBO3: Tb3+ phosphor for white LEDs, J. Rare Earths, 28 (2010) 30-33.

DOI: 10.1016/s1002-0721(09)60044-2

Google Scholar

[3] M. Bredol, S. Gutzov. Highly efficient energy transfer from Ge-related defects to Tb3+ ions in sol-gel derived glass, J. Non–Cryst. Solids, 321 (2003) 225-230.

DOI: 10.1016/s0022-3093(03)00225-4

Google Scholar

[4] L. Wang, L. Shi, N. Liao, Photoluminescence properties of Y2O3: Tb3+ and YBO3: Tb3+ green phosphors synthesized by hydrothermal method, Mater. Chem. Phys., 119 (2010) 490-494.

DOI: 10.1016/j.matchemphys.2009.10.002

Google Scholar

[5] C.B. Rubinstein, L.G. Van Uitert, W.H. Grodkiewicz, Program of the Twenty-Second Annual Meeting of the Electron Microscopy Society of America, J. Appl. Phys., 35 (1964) 3074-3102.

DOI: 10.1063/1.1713186

Google Scholar

[6] M.Y.A. Raja, D. Allien, W. Sisk, Room-temperature inverse Faraday effect in terbium gallium garnet , Appl. Phys. Lett., 67 (1995) 2123-2125.

DOI: 10.1063/1.114740

Google Scholar

[7] B. Sugg, H. Nurge, B. Faust, The photorefractive effect in terbium gallium garnet, Opt. Matter, 4 (1995) 343-347.

DOI: 10.1016/b978-0-444-82167-6.50045-2

Google Scholar

[8] C. Robert Linares, Growth of Garnet Laser Crystals, Solid States Comm., 2 (1964) 229-231.

Google Scholar

[9] A.S. Aleksandrovsky, A.V. Malakhovskii, V.N. Zabluda, Optical and magneto-optical spectra of europium-doped strontium tetraborate single crystals, J. Phys. Chem. Solids, 67 (2006) 1908-(1912).

DOI: 10.1016/j.jpcs.2006.04.008

Google Scholar

[10] W. He, J. Zhang, Q.S. Zhang, Synthesis and Characterization of SmBO3 by So1. Gel Combustion Method, Rare Met., 33 (2009) 348-351.

Google Scholar

[11] D. Zhao, Z.S. Hu, Z.B. Lin, G.F. Wang, Growth and spectral properties of Er3+/Yb3+ -codoped Sr3Y(BO3)3 crystal, J. Cryst. Growth, 277 (2005) 401-405.

DOI: 10.1016/j.jcrysgro.2005.01.081

Google Scholar

[12] G. Chadeyron, M. El-Ghozzi, R. Mahiou, Revised Structure of the Orthoborate YBO3, J. Solid States Chem., 128 (1997) 261-266.

DOI: 10.1006/jssc.1996.7207

Google Scholar

[13] H.J. Li, Synthesis, characterization and crystal structure of novel transition metal borates, Shanxi Normal University, Xi'an, (2007).

Google Scholar

[14] R.E. Newnham, M.J. Redman, Ceramic abstracts, J. Am. Ceram. Soc., 46 (1963) 235-264.

Google Scholar

[15] M. Ren, J.H. Lin, Y. Dong, L.Q. Yang, Structure and phase transformation of GdBO3, Chem. Mater., 11 (1999) 1576-1580.

Google Scholar

[16] G. Corbel, M. le Blanc, E. Antic-Fidancev, M. Lemaitre-Blaise, Luminescence analysis and subsequent revision of crystal structure of triclinic L - (EuBO3), J. Alloys Compd., 287 (1999) 71-78.

DOI: 10.1016/s0925-8388(99)00023-7

Google Scholar