Synthesis and Luminescent Properties of New Oligofluorene Derivatives Containing Various Comonomers

Article Preview

Abstract:

Two kinds of oligofluorenes containing acetylene units are synthesized by Sonogashira coupling reaction. naphthalene and anthracene are co-polymerized with ethynylfluorene, respectively. The structure and properties are characterized using NMR, UV-vis spectroscopy, elemental analysis, DSC and photoluminescence. The oligomers are soluble in common organic solvents such as benzene and easily spin-coated onto glass substrates. The products yield strong emission differing from blue to green-yellow, and red-shift are suppressed with the growth in size of co-monomers.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 314-316)

Pages:

2227-2231

Citation:

Online since:

August 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burn, A. B. Holmes: Nature, 347 (1990), p.539

Google Scholar

[2] A. C. Grimsdale, K. L. Chan, L. E. Martin, P. G. Jokisz, A. B. Holmes: Chem. Rev., 109 (2009), p.897

Google Scholar

[3] Y. Lim, Y. S. Park, Y. Kang, D. Y. Jang, J. H. Kim, J. Kim, A. Sellinger and D. Y. Yoon: J. Am. Chem. Soc., 133 (2011), p.1375

Google Scholar

[4] Q. Pei, Y. Yang: J. Am. Chem. Soc., 118 (1996), p.7416

Google Scholar

[5] X. Chen, J. L. Liao, Y. Liang, M. O. Ahmed, H. E. Tseng, S. A. Chen: J. Am. Chem. Soc., 125 (2003), p.636

Google Scholar

[6] U. Scherf, D. Neher, Polyfluorene, Springer-Verlag, Berlin, (2008)

Google Scholar

[7] Q. Peng, J. Xu, M. Li, W. Zhen, Macromolecules, 42 (2009), p.5478

Google Scholar

[8] Z. Chu, D. Wang, C. Zhang, X. F, Y. Tang, L. Chen, D. Zou: Macromol. Rapid Commun., 30 (2009), p.1745

Google Scholar

[9] E. J. W. List, R. Guenter, P. Scanducci de Freitas, U. Scherf : Adv. Mater., 14 (2002), p.374

Google Scholar

[10] L. Romaner, A. Pogantsch, P. Scanducci de Freitas, U. Scherf, M. Gaal, E. Zojer, E. T. W. List: Adv. Func. Mater.,13 (2003), p.597

DOI: 10.1002/adfm.200304360

Google Scholar

[11] H. H. Lu, C. Y. Liu, T. H. Jen, J. L. Liao, H. E. Tseng, C. W. Huang, M. C. Hung, S. A. Chen: Macromolecules, 38 (2005), p.10829

Google Scholar

[12] G. Klarner, M. H. Davey, W. D. Chen, J. C. Scott, R. D. Miller: Adv. Mater., 10 (1999), p.993

Google Scholar

[13] V. N. Bliznyuk, S. A. Carter, J. C. Scott, G. Klarner, R. D. Miller, D. C. Miller: Macromolecules, 32 (1999), p.361

Google Scholar

[14] X. D. Hu, L. Su, Q. Liao, C. Zhen, Y. Chuai, D. C. Zou; Chemical Journal of Chinese Universities, 10 (2005), p. (1900)

Google Scholar