Sorption and Desorption of DDTs to Natural Surface Coatings

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The sorption/desorption of DDTs to surface coatings were investigated using the bath equilibration technique. Freundlich isotherm was applied to describe the sorption/desorption of DDTs to surface coatings. The results showed that desorption of DDTs from surface coatings presented hysteresis which was described by hysteresis index (HI). Influences of pH values of solutions and the coexistence of Cu and Pb on sorption and desorption were also studied in the same method. The results indicated that the sorption of DDTs decreased and desorption increased when the values of pH increased from 5 to 9. The coexistence of Cu and Pb inhibited the sorption of DDTs, meanwhile had facility to desorption of DDTs.

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125-128

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August 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Tao, F.L. Xu, X. J. Wang, et al. Organochlorine pesticides in agricultural soil and vegetables from Tianjin, China. Environmental Science and Technology. (2005).

Google Scholar

[2] Y. Shi, F. Meng, F. Guo, Y. Lu, T. Wang and H. Zhang. Residues of Organic Chlorinated Pesticides in Agricultural Soils of Beijing, China. Archives of Environmental Contamination and Toxicology. (2005).

DOI: 10.1007/s00244-004-0087-z

Google Scholar

[3] S.H. Guo, Y. Li, L. Liu and X.Y. Hua. Adsorption of Pb and Cd on the natural surface coatings(NSCs) in the presence of organochlorine pesticides: A preliminary investigation. Journal of Environmental Management. (2008).

DOI: 10.1016/j.jenvman.2007.02.001

Google Scholar

[4] A.T. Kan, G. Fu and M.B. Tomson. Adsorption/desorption hysteresis in organic pollutant and soil/sediment interaction. Environmental Science and Technology. (1994).

DOI: 10.1021/es00054a017

Google Scholar

[5] D.M. Dong, Y. Li, J.J. Zhang and X.Y. Hua. Comparison of the adsorption of lead, cadmium, copper, zinc and barium to freshwater surface coatings. Chemosphere. (2003).

DOI: 10.1016/s0045-6535(02)00835-4

Google Scholar

[6] W.L. Huang and W.J. Weber. A Distributed Reactivity Model for Sorption by Soils and Sediments. 10. Relationships between Desorption, Hysteresis, and the Chemical Characteristics of Organic Domains. Environmental Science and Technology. (1997).

DOI: 10.1021/es960995e

Google Scholar

[7] R.L. Dai, G.Y. Zhang, X.Z. Gu, M.K. Wang. Sorption of 1, 1, 1-trichloro-2, 2-bis(p-chlorophenyl) ethane (DDT) by clays and organoclays. Environmental Geochemistry and Health. (2008).

DOI: 10.1007/s10653-007-9130-0

Google Scholar

[8] M. Sander, Y. Lu and J.J. Pignatello. A thermodynamically based method to quantify true sorption hyseresis. Journal of Environmental Quality. (2005).

DOI: 10.2134/jeq2004.0301

Google Scholar

[9] S.D. Haigh. A review of the interaction of surfactants with organic contaminants in soil[J]. Science of The Total Environment. (1996).

Google Scholar