Preparation and Structural Characterization of Chain Ni (II) Coordination Polymer Material

Abstract:

A chain Ni (II) coordination polymer material was prepared and characterized by elemental analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.24348(13) nm, b = 1.29477(12) nm, c = 1.51480(17) nm and Dc = 1.401 g•cm-3. The results of structural analysis indicated that each Ni (II) ion forms six-coordinated with nitrogen atoms of pyridine and thiocyanate, and the Ni (II) coordination polymer material formed one dimensional chain structure by the interaction of pyridine rings.

• Periodical: Advanced Materials Research (Volume 322)
• Pages: 369-372
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.322.369
• Online since: August 2011
• Authors: Zhi Xiang Ji
• Keywords: Material, Ni (II) Coordination Polymer, Preparation, Structural Characterisation

References

[1] B. Y. Liu, Z. Liu, J. H. Xia: Chinese J. Inorg. Chem. 27 (2011), 797.

[2] B. Chen, M. Eddaoudi, S. T. Hyde: Science. 291 (2001), 1021.

[3] G. A. Santillan, C. J. Carrano: Inorg. Chem. 47 (2008), 930.

[4] E. M. Bauer, C. Bellitto, G. Righini: Inorg. Chim. 47 (2008), 10945.

[5] G. M. Sheldrick, SHELXL-97, Program for Solution of crystal structures, University of Göttingen, Germany, (1997).

[6] G. M. Sheldrick, SHELXS 97, Program for Refinement of Crystal structures, University of Göttingen, Germany, (1997).