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Electrochemically Synthesis and Characterization of Copolymers Based on 1, 4-Diethoxybenzene and 3, 4-Ethylenedioxythiophene

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Abstract:

Copolymers based on 1, 4-diethoxybenzene (DEB) and 3, 4-ethylenedioxythiophene (EDOT) were electrochemically synthesized and characterized. The structures of the copolymers were established by 1H NMR and FT-IR spectroscopy. The results indicated the final product was a copolymer instead of a blend or a composite. The physical properties were systematically investigated by cyclic voltammetry, UV-vis absorption and fluorescence. The PL maximum of copolymers presented obviously red-shift to long wavelength as the feed ratio of EDOT in monomer mixture increased.

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Periodical:

Advanced Materials Research (Volumes 335-336)

Pages:

989-993

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.335-336.989

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Online since:

September 2011

Authors:

Mi Ouyang, Zhen Wei Yu, Yi Xu, Yu Jian Zhang, Cheng Zhang

Keywords:

Copolymer, Electrochemical Polymerization, PEDOT, Photoluminescence (PL)

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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