Chemical Fractionation and Bioavailability of Cd, Ni, Cu, Zn and Pb in Sewage-Irrigated Soils from Xiaoqing River, Zhangqiu Area, China

Article Preview

Abstract:

The total contents and chemical phase partitioning of Cd, Ni, Cu, Zn and Pb from long-time sewage- irrigated soil were analyzed in this paper. The results showed that the contents of Ni, Cu, Zn, and Pb did not exceed the the second-level limit of Standard of Soil Environment (GB15618-1995), but the average content of Cd was 1.81 mg•kg-1, which was about three times more than the national standard. The chemical partitioning of metals analysis showed that Cd was present dominantly in the acetic acid extractable fraction with the average percentage of 37.44%, while the other four elements mostly in residual fraction, which indicated that Cd had the highest bioavailability, mobility and phyto-toxicity. Compared to the well-irrigated soils, the percentages of acetic acid extractable fractions of Cd, Ni, Zn and Cu were obviously higher in the contaminated soils, which increased the potential danger of heavy metals pollution.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 356-360)

Pages:

891-895

Citation:

Online since:

October 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Sastre J,Hernandez E,Rodriguez R,et al.,Use of sorption and extraction tests to predict the dynamics of the interaction of trace elements in agricultural soils contaminated by a mine tailing accident[J],Science of the Total Environment, 2004,329:261-281.

DOI: 10.1016/j.scitotenv.2004.03.012

Google Scholar

[2] Ladonin D V.Heavy metal compounds in soils:problems and methods of study[J],Eurasian.Soil Sci.,2002,35(6):605-613.

Google Scholar

[3] Bermond A.Limits of sequential extraction procedures re-examined with emphasis on the role of H+ion reactivity[J].Anal.Chim.Acta,2001,445:79-88.

DOI: 10.1016/s0003-2670(01)01237-5

Google Scholar

[4] Impellitteri C A,Saxe J K,Cochran M,et al.Predicting the bioavaillability of copper and zinc in soils:Modeling the partitioning of potential bilavailable copper and zinc from solid to soil solution[J]. Environmental Toxicology and Chemistry, 2003, 22(6):1380-1386

DOI: 10.1002/etc.5620220626

Google Scholar

[5] StevensD P, McLaughlinM J, SmartM K·Effectof long term with reclaimed water on soils of the Northern Adelaide Plains, South Australia[J]·Australian JournalofSoilResearch, 2003(41): 933-948·

DOI: 10.1071/sr02049

Google Scholar

[6] HeidarpourM, Mostafazadeh-Fard, AbediKoupai B J, et al·The effects of treated wastewater on soil chemical propertiesusing subsurface and surface irrigationmethods[J]·AgriculturalWaterManagement, 2007, 90: 87-94·

Google Scholar

[7] AielloR, CirelliG L, ConsoliS·Effects of reclaimedwastewater irrigation on soiland tomato fruits: a case study in Sicily (Italy) [J]AgriculturalWaterManagement, 2007, 93(13): 65-72·

Google Scholar

[8] Lu Rushen. Chemical analysis method of soil agriculture [M].Beijing : Chinese agriculture science and technique book concern,2000.

Google Scholar

[9] Rauret G,López-Sánchez J F,Sahuquillo A U,et al.Improvement the BCR three-step sequential extraction procedure prior to tcertification of new sediment and soil reference materials[J].Jour of Environmental Monitoring,1999,1:57-61.

DOI: 10.1039/a807854h

Google Scholar

[10] Cheng Jiemin, Pan Genxing ,Zheng Jinwei  et al. Effect of simulated acid rain on adsorption and desorption of copper by paddy soils in Taihu Lake region. [J]. Acta Pedologica Sinica,2001,38(3):333-340.

Google Scholar

[11] Singh, K. P., Mohan, D., Singh, V. K., et al. Studies on distribution and fractionation ofheavymetals in Gomti river sediments - a tributary of the Ganges, India[J]. J.Hydro.l 2005.312: 14-27.

DOI: 10.1016/j.jhydrol.2005.01.021

Google Scholar

[12] Jain, C. K., Metal fractionation study on bed sediments of riverYamuna, India[J].WaterRes. 2004.38:569-578.

Google Scholar

[13] Ding Jiang hua; Wen Yanmao; Shu Qiang. Fraction Transformation of Cadmium and Zinc in Soils [J]. Urban Environment and Urban Ecology,2001,14(2):47-49.

Google Scholar