The Research on Dissolving Properties of Biodegradable Cellulose Pulp

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For making Eco-Friendly cellulose sponge, cellulose pulp dissolving properties were researched in this paper. NaOH and NaOH/Urea solutions were both used, various factors (temperature, concentration and time) on viscosity of the pulp were studied. At first, ten different kinds of cellulose pulps were dissolved at low temperature in a certain range of concentration of NaOH solvent and the pulp with best soluble property was chosen. On the above basis, effects of the temperature of alkaline solvent and concentration on the viscosity of the selected pulp was fatherly experimented and analyzed. The result was got that at concentration of 8% of NaOH solution and at temperature of -5°C, the cellulose pulp has the best solubility. In the meantime, the solution has the biggest viscosity. On the other hand, NaOH/Urea solvent was tested for cellulose solubility. After experiment, the tests showed that when NaOH/Urea blending ratio is 8:12, the selected pulp solves completely and the solution was clear. Thus NaOH/Urea solvent has better solubility than that of NaOH solution for solving the cellulose pulp.

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Advanced Materials Research (Volumes 383-390)

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3998-4002

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November 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.F. Shi, Z. M. Wang, and S.Y. Guo, New Solvent Systems of Cellulose, Journal of Cellulose Science and Technology, vol. 15,. pp.74-78, March (2007).

Google Scholar

[2] A. Li, L. N, Zhang, Advance in Solvents of Cellulose, " Acta Polymerica Sinica, pp.937-942, October (2007).

Google Scholar

[3] A.M. Bochek, Effect of Hydrogen Bonding on Cellulose Solubility,. Russian Journal of Applied Chemis-try, vol. 11,. pp.1713-1718, November (2003).

Google Scholar

[4] C. Jie, L.N. Zhang,. Rapid Dissolution of Cellulose in LiOH/urea and NaOH/urea Aqueous Solutions,. Macromolecular Bioscience, vol. 5,. pp.539-548, June (2005).

DOI: 10.1002/mabi.200400222

Google Scholar

[5] L.N. Zhang, D. Ruan, S.J. Gao, Dissolution and Regener-ation of Cellulose in NaOH/ Thiourea Aqueous Solution, Journal of Polymer Science, vol. 40,. pp.1521-1529, June (2002).

DOI: 10.1002/polb.10215

Google Scholar

[6] C. Jie, L.N. Zhang, C.Y. Chang, Hydrogen-bond-induced Inclusion Complex in Aqueous Cellulose/ LiOH/ urea Solution at Low Temperature, Chemical Physics and Physical Chemistry, vol. 10,. pp.1572-1579, August (2007).

DOI: 10.1002/cphc.200700229

Google Scholar

[7] A. Isogai, R. H. Atalla, Dissolution of Cellulose in Aqueous NaOH Solutions, Cellulose, vol. 4,. p.309–319, May (1998).

Google Scholar

[8] H. Jin, C. Zha, and L. Gu. Direct Dissolution of Cellulose in NaOH/thiourea/urea Aqueous Solution,, Carbohydrate Research,vol. 342,. pp.851-858, May (2007).

DOI: 10.1016/j.carres.2006.12.023

Google Scholar

[9] C. Jie, L.N. Zhang,. Rapid Dissolution of Cellulose in LiOH/urea and NaOH/urea Aqueous Solutions,. Macromolecular Bioscience, vol. 6,. p.539–548, May (2005).

DOI: 10.1002/mabi.200400222

Google Scholar