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Selectivity Patterns of Radical Reactions in 1-Hexene Pyrolysis

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Abstract:

The pyrolysis of 1-hexene at 873 K was investigated. Primary products include C1-C4 paraffins, C2-C4 olefins, butadiene, pentadiene, cyclopentane, cyclopentene, coke and hydrogen. A chain reaction mechanism was developed to interpret the distribution of products, and the quantitative analysis on the selectivity patterns of radical reactions was presented.

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Periodical:

Advanced Materials Research (Volumes 391-392)

Pages:

1406-1411

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.391-392.1406

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Online since:

December 2011

Authors:

Ying Xian Zhao

Keywords:

1-Hexene, Chain Mechanism, Free Radical, Pyrolysis, Selectivity Patterns

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] M. Yahyaoui: Proceedings of the Combustion Institute Vol. 30 (2005), p.1137.

Google Scholar

[2] J.H. Kiefer, K.S. Gupte, and S.J. Klippenstein: J. Phys. Chem. A Vol. 113 (2009), p.13570.

Google Scholar

[3] H. Wang, F. Yang, X. Ran, Z. Shi and Z. Wen: J. Mol. Structure Vol. 710 (2004), p.179.

Google Scholar

[4] W. Tsang: J. Chem. Kinetics Vol. 10 (2004), p.1119.

Google Scholar

[5] Y.X. Zhao, F. Wei and Y. Yu: AIChE J. Vol. 54 (2008), p.750.

Google Scholar

[6] R. Bounaceur: J. Anal. Appl. Pyrolysis Vol. 64 (2002), p.103.

Google Scholar

[7] J.A. Franz, D.M. Camaioni, T. Autrey, J.C. Linehan and M.S. Alnajjar: J. Anal. Appl. Pyrolysis Vol. 54 (2000), p.37.

Google Scholar

[8] Y. Xiao, J.M. Longo, G.B. Hieshima and R.J. Hill: Ind. Eng. Chem. Res. Vol. 36 (1997), p.4033.

Google Scholar

[9] I.A. Wiehe: Ind. Eng. Chem. Res. Vol. 31 (1992), p.530.

Google Scholar

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