Spectral Properties of Alpha-Cu2(OH/D)3Br at Room Temperature

Xiao Dong Liu; Dong Dong Meng; Xu Guang Zheng; Qi Xin Guo

doi:10.4028/www.scientific.net/AMR.391-392.1493

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 391-392Spectral Properties of Alpha-Cu2(OH/D)3Br at Room...

Spectral Properties of Alpha-Cu₂(OH/D)₃Br at Room Temperature

Abstract:

The newly identified magnetic geometric frustration material-botallackite-structure deuteroxyl copper bromide α-Cu₂(OD)₃Br sample was successfully synthesized in the same single phase (polycrystalline) as the H-isotope substituted sample of α-Cu₂(OH)₃Br, and its IR (4000-400 cm^–1) absorption and Raman (4000-95 cm^–1) spectra at room temperature are first, to the best of our knowledge, measured to study the corresponding relationship between these iso-structural compounds. Through the comparative analysis with those of α-Cu₂(OH)₃Br reported previously, we definitely assign or tentatively suggest their vibration modes according to the result of the factor group analysis.

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Advanced Materials Research (Volumes 391-392)

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1493-1497

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https://doi.org/10.4028/www.scientific.net/AMR.391-392.1493

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Online since:

December 2011

Authors:

Xiao Dong Liu, Dong Dong Meng, Xu Guang Zheng, Qi Xin Guo

Keywords:

Deuteroxyl Copper Bromide, Factor Group Analysis, Geometrical Frustration, IR-Spectrum, Raman Spectrum

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