A Novel Gold Nanoparticle/Poly(AMPS-co-HEMA) Composite Hydrogel for Selective Catalysis

Abstract:

A modified seed-mediated growth method was developed for in situ controllable preparation of gold nanoparticles (GNPs) within P(AMPS-co-HEMA) hydrogel networks. When the time of cycles absorbing procedure increased in mother solutions under given temperature during the processing stage, the number of GNPs was significantly increased and networks were utilized for in situ nanoparticles synthesis by reduction of glod ion absorbed. TEM images confirmed that GNPs were between 100 and 200 nm in size and distributed uniformly in gel. The network embedded GNPs also endows the composite gel with selective catalytic activity for selective catalysis in the reduction of nitro compound (2-NP, 3-NP and 4-NP). The kinetics of the reduction reaction were investigated under the same condition, the result showed the GNPs gel system was found to have an excellent catalytic activity and high conversion for 4-NP reduction among nitrophenol homologue, the nitrophenol hydrogenation rate got to 6.63 mol/g min for reducing of 4-NP compared to 3.69 mol/g min, the rate of 2-NP. It was almost zero for 3-NP implying no catalytic activity, even though they were isomeride.

• Periodical: Advanced Materials Research (Volumes 399-401)
• Pages: 704-707
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.399-401.704
• Online since: November 2011
• Authors: Ke Ping Wang, Song Bai Lin, Na Na Wang, Ai Ru Ke
• Keywords: Elective Catalysis, Gold Nanoparticles (GNP), In Situ Controllable, Modified Seed-Mediated Growth Method

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