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Solvothermal Synthesis and Photocatalysis of SnO2 Nanocrystal Microspheres
Abstract:
Quasi-monodispersed SnO2 nanocrystal microspheres were successfully fabricated by a solvothermal route with the assistance of poly (ethylene glycol) (PEG, Mn=6000) template. The as-prepared SnO2 microspheres were well characterized by XRD, SEM, TEM, and FT-IR. The photocatalytic activity for Rh B on the SnO2 microspheres was also investigated under UV irradiation. The experimental results show that the quasi-monodispersed SnO2 microspheres with diameter about 1.3µm are self-assembled by large quantity of crystallites less than 10 nm. The SnO2 microspheres have a good photocatalytic property, as evidenced by the result that over 95% of the Rh B decomposed over the SnO2 nanocrystal microspheres within 180 min. The high degradation rate of rhodamine B (Rh B) on the as-synthesized SnO2 nanocrystal microspheres can be attributed to the small size of crystals.
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40-43
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November 2011
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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