Preparation and Properties of Castor Oil-Based Waterborne Polyurethane Terminated

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Abstract:

Prepared a series of castor oil modified NaHSO3 waterborne blocked polyurethane, discussed the influence on the emulsion stability by C.O. addition amount, R value, DMPA and the influences on latex film mechanical property and water absorption by C.O. content, R value. Then analyzed the characterization by FTIP and DSC, its shown that emulsion is stable when the R value controlled in the range of 1.4~1.8 and the stability will become poor with the increase of C.O. content; and with the increase of R value the elongation at break of latex film reduced and tensile strength increased. In short the C.O.s mixing can make latex film initial decomposition temperature increased by 60, reduced elongation at break, increased tensile strength and reduced the water absorption.

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98-103

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. L. Yang, D. A. Wick and Hoyle CE, et al.: Newly UV-curable polyurethane coatings prepared by multifunctional thiol and eneteminated polyurethane aqueous dispersions mixtures: prepared and Characterization. Polymer, Vol. 50(2009), pp.1717-1722.

DOI: 10.1016/j.polymer.2008.12.018

Google Scholar

[2] E. Shi, W. X. Huang and Z. Y. Xiao, et al.: Tang, Influence of binding interface between active and sup-port layers in composite PDMS membranes on permeation performance. Journal of Applied Polymer Science. Vol. 104(2007), pp.2468-2477.

DOI: 10.1002/app.25358

Google Scholar

[3] M. A. Eddings and B. k. Gale: A PDMS-based gas pea-ton pumps for on-chip fluid handling in microfluidic devices. Journal of Micromechanics and Micro- engineering. Vol. 16(2006), pp.2396-2402.

DOI: 10.1088/0960-1317/16/11/021

Google Scholar

[4] H. Q. Jiang, Z. Q. Song, S. B. Shang, et al. Preparation and properties of castor oil-modified waterborne polyurethane emulsion. Chemical Industry and Engineering Progress. Vol. 29(2010), pp.285-287.

Google Scholar

[5] C. Wang, Y.S. Wu and L.L. Wu: Study on Synthesis and Properties of MDI Based Aqueous Polyurethane Dispersion. Paint & Coatings Industry, Vol. 39 (2009), pp.4-8.

Google Scholar

[6] H. Du, N. Yin and Y. H. Zhao, et al.: Preparation and characterization of polyurethane elastomer based on castor oil-polyether polyol. New Chemical Materials, Vol. 37 (2009), pp.106-108.

Google Scholar