Preparation of Epoxy/PEG Shape-Stabilized Phase Change Materials by In Situ Reactive Blending

Article Preview

Abstract:

Recently, solid-liquid phase change materials (PCMs) have caused much attention due to their large latent heat. In order to solve their sealed problem, shape-stabilized methods have become a popular research topic. In this study, we prepared epoxy/polyethylene glycol (PEG) shape-stabilized PCMs with different mass ratios successfully by in-situ reactive blending. The maximum mass percentage of PEG dispersed into epoxy to form epoxy/PEG shape-stabilized PCM was determined as 70wt % by observing the morphology at the temperature above the phase transition. The thermal properties, such as melting temperature, latent heat, were measured by DSC. The results showed that the melting temperatures ranged from 55.5 OC to 60.4 OC and the latent heat was proportional to the mass percentage of PEG.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 430-432)

Pages:

1023-1027

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Sarı A, Biçer A, Karaipekli A. Synthesis, characterization, thermal properties of a series of stearic acid esters as novel solid–liquid phase change materials. Mater Lett 2009; 63: 1213-1216.

DOI: 10.1016/j.matlet.2009.02.045

Google Scholar

[2] Alkan C, Kaya K, Sarı A. Preparation and thermal properties of ethylene glycol distearate as a novel phase change material for energy storage. Mater Lett 2008; 62: 1122-1125.

DOI: 10.1016/j.matlet.2007.07.061

Google Scholar

[3] Akamtsu Y, Kunyone M. Heat-storage materials and air conditioning systems. JP 08104886, (1996).

Google Scholar

[4] Kenisarin M, Mahkamov K. Solar energy storage using phase change materials. Renew Sustain Energy Rev 2007; 11: 1913–(1965).

DOI: 10.1016/j.rser.2006.05.005

Google Scholar

[5] Zhang YP, Lin KP, Zhang QL, Ding HF. Ideal thermophysical properties for free-cooling (or heating) buildings with constant thermal physical property material Energ Build 2006; 38: 1262–1269.

DOI: 10.1016/j.enbuild.2006.01.008

Google Scholar

[6] Atul S, Tyagi VV, Chen CR, Buddhi D. Review on thermal energy storage with phase change materials and applications. Renew Sustain Energy Rev 2009; 13(2) 318–345.

DOI: 10.1016/j.rser.2007.10.005

Google Scholar

[7] Jiang Y, Ding EY, Li GK. Study on transition characteristics of PEG/CDA solid–solid phase change materials. Polym 2002; 43: 117-122.

DOI: 10.1016/s0032-3861(01)00613-9

Google Scholar

[8] Su JC, Liu PS. A novel solid–solid phase change heat storage materials with polyurethane block copolymer structure. Energ Convers Manag 2006; 47: 3185–3191.

DOI: 10.1016/j.enconman.2006.02.022

Google Scholar

[9] Chen CZ, Wang LG, Huang Y. A novel shape-stabilized PCM: Electrospun ultrafine fibers based on lauric acid/polyethylene terephthalate composite. Mater Lett 2008; 62: 3515-3517.

DOI: 10.1016/j.matlet.2008.03.034

Google Scholar

[10] Wang WL, Yang XX, Fang YT, Ding J. Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage. Appl Energ 2009; 86: 170-174.

DOI: 10.1016/j.apenergy.2008.12.004

Google Scholar