Cu (II), Zn (II) Complexes Containing Calix [4] Arene Modified by Salicylaldehyde Acylhydrazone - Synthesis, Properties and Application

Abstract:

Two complexes L(MAcO)₂ (M=Cu, Zn) containing calix [4] arene ligand H₂L modified by salicylaldehyde acylhydrazone have been synthesized and characterized by elemental analysis, MS(ESI), IR, UV-vis and fluorescence. Whereas L(ZnAcO)₂ exhibited an enhancement in fluorescence, the potentiality of H₂L acting as a Zn²⁺- selective fluorescence probe was investigated. Results showed that a good linearity (correlation coefficient 0.999) between fluorescence intensity and concentration of Zn²⁺ in range of 4.0×10^-6 mol·L^-1 ~ 4.0×10^-5 mol·L^-1 existed in H₂L solution of 1.0×10^-4 mol·L^-1. The minimum concentration at which H₂L could detect Zn²⁺ was 1.0 ×10^–6 mol·L^-1. Co-existence of Cu²⁺, Ni²⁺ and Mn²⁺ would interfere the determination of Zn²⁺, but no influence by Na⁺, Mg²⁺, Cd²⁺ and Pb²⁺.

• Periodical: Advanced Materials Research (Volumes 455-456)
• Pages: 1244-1250
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.455-456.1244
• Online since: January 2012
• Authors: Xiao Mei Zhang, Guo Cai Xu, Jia Long Sun
• Keywords: Complex, Cu²⁺, Salicylaldehyde Acylhydrazone Calix [4] Arene, Zn²⁺, Zn²⁺-Selective Fluorescence Probe

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