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Two-Dimensional Neutral Framework Generated from Mixed Organic Ligands: Structure and Magnetic Properties

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Abstract:

A new two-dimensional neutral framework generated from mixed organic ligands [Cu3(1,2,4-BTC)2(4,4/-bipy)(H2O)4] (where1,2,4-BTC = 1,2,4-benzenetricarboxylate), has been prepared under hydrothermal condition and characterized by single crystal X-ray diffraction and magnetic susceptibilities. Its structure contains two different one-dimensional chains for the Cu ions, namely [Cu2(1,2,4-BTC)2]n2n- and [Cu (4,4/-bipy)]n2n+, respectively; the carboxylate of 1,2,4-BTC ligands links the two different 1-D chains into a interesting steplike supramolecular neutral framework, which exists ferromagnetic interactions between the copper centers.

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Periodical:

Advanced Materials Research (Volumes 455-456)

Pages:

735-739

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.455-456.735

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Online since:

January 2012

Authors:

Rui Xin Chen, Ling Yan Xu, Chang Feng Sun

Keywords:

Crystal Structure, Hydrothermal Synthesis, Magnetic Property

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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