Degradation of ABS in ABS/CaCO3 Composites during Reprocessing

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Abstract:

Acrylonitrile-Butadiene-Styrene (ABS)/CaCO3 composites were reprocessed under normal conditions. The effects of reprocessing on the degradation of ABS were investigated by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). The mechanical properties of the reprocessed materials were measured. In this paper, a method to evaluate the degradation of ABS in ABS/CaCO3 composites by FTIR was described. The results show that within the range of the reprocessing cycles studied, as the number of reprocessing cycles increased, the impact strength of composite was significantly reduced if the content of CaCO3 is lower than 10%, due to the degradation of rubber phase. However, the impact strength was almost unchanged when the content of CaCO3 was higher than 15%.

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Advanced Materials Research (Volumes 455-456)

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845-850

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Y. Tang and C. E. Chaffey, Mechanical and flow properties of recycled filled polystyrene, Plastics and Rubber Processing and Applications, vol. 12, no. 1, pp.53-61, (1989).

Google Scholar

[2] G. Guerrica-Echevarría, J. I. Eguiazábal, and J. Nazábal, Effects of reprocessing conditions on the properties of unfilled and talc-filled polypropylene, Polymer Degradation and Stability, vol. 53, no. 1, pp.1-8. (1996).

DOI: 10.1016/0141-3910(96)00018-3

Google Scholar

[3] S. Covavisaruch, S. Tangratanasophon, and S. Pisitpong, Effects of the number of recycling passes on high impact polystyrene, The 4th World Congress on Recovery, Recycling and Re-integration, Geneva, Switzerland, vol. 3, pp.443-447, 1999.

Google Scholar

[4] G. M. Russo, V. Nicolais, L. Di Maio, S. Montesano, and L. Incarnato, Rheological and mechanical properties of nylon 6 nanocomposites submitted to reprocessing with single and twin screw extruders, Polymer Degradation and Stability, vol. 92, no. 10, pp.1925-1933, October (2007).

DOI: 10.1016/j.polymdegradstab.2007.06.010

Google Scholar

[5] E. -K. Karahaliou and P. A. Tarantili, Preparation of poly(acrylonitrile-butadiene-styrene)/montmorillonite nanocomposites and degradation studies during extrusion reprocessing, Journal of Applied Polymer Science, vol. 113, no. 4, pp.2271-2281, (2009).

DOI: 10.1002/app.30158

Google Scholar

[6] J. K. Kim and C. K. Kang, Basic studies on recycling of ABS resin, Polymer-Plastics Technology and Engineering, vol. 34, no. 6, pp.875-890, (1995).

DOI: 10.1080/03602559508012182

Google Scholar

[7] J. I. Eguiazábal and J. Nazábal, Reprocessing polycarbonate/acrylonitrile-butadiene-styrene blends: Influence on physical properties, Polymer Engineering and Science, vol. 30, no. 9, pp.527-531, (1990).

DOI: 10.1002/pen.760300905

Google Scholar

[8] H. Kohkame, H. Asano, M. Goto, and Y. Miyano, Analysis of thermal stability of acrylonitrile-acrylic elastomer-styrene terpolymer in injection molding, Polymer Engineering and Science, vol. 33, no. 10, pp.607-613, (1993).

DOI: 10.1002/pen.760331005

Google Scholar

[9] D. Dong, S. Tasaka, S. Aikawa, S. Kamiya, N. Inagaki, and Y. Inoue, Thermal degradation of acrylonitrile–butadiene–styrene terpolymer in bean oil, , Polymer Degradation and Stability, vol. 73, no. 2, pp.319-326, (2001).

DOI: 10.1016/s0141-3910(01)00093-3

Google Scholar

[10] W. Wang, G. Wang, X. Zeng, L. Shao, and J. Chen, Preparation and properties of nano-CaCO3/acrylonitrile-butadiene-styrene composites, Journal of Applied Polymer Science, vol. 107, no. 6, pp.3609-3614, (2008).

DOI: 10.1002/app.27285

Google Scholar

[11] A. Zhang, G. Zhao, Y. Guan, and G. Chen, Study on mechanical and flow properties of acrylonitrile-butadiene-styrene/poly (methyl metharylate)/ nano-calcium carbonate composites, Polymer Composites, vol. 31, no. 9, pp.1593-1602, September (2010).

DOI: 10.1002/pc.20947

Google Scholar

[12] A. Boldizar and K. MÖller, Degradation of ABS during repeated processing and accelerated ageing, Polymer Degradation and Stability, vol. 81, no. 2, pp.359-366, (2003).

DOI: 10.1016/s0141-3910(03)00107-1

Google Scholar