Study on Curing Kinetics of a Novel Epoxy Resin System for Hot-Melt Prepreg

Article Preview

Abstract:

The curing kinetics of the novel epoxy system for hot-melt prepreg was investigated using nonisothermal differential scanning calorimetry (DSC), and determined by Kissinger, Ozawa and Crane methods in this paper. The results showed that the value of Ti, Tp, and Tf were 446.5K, 454.7K, 491.4K, respectively. Furthermore the value of Ea1 and Ea2 determined by Kissinger and Ozawa method, respectively, were approximate, and the mean value of activation energy (Ea) is 139.31 KJ/mol. The value 0.9488 of curing reaction order n indicated that the curing reaction was complex reaction.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 457-458)

Pages:

453-456

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] N. Kinjo, M. Ogata, K. Nishi and A. Kaneda: Adv. Polym. Sci, Vol. 88 (1989) p.1–48.

Google Scholar

[2] P.B. Messersmith and E.P. Giannelis: Chem. Mater, 6 (1994) p.719–1725.

Google Scholar

[3] H. Kishi, M. Tokunoh , U.S. Patent 6, 228, 474. (2001).

Google Scholar

[4] D E. Kissinger: Anal. Chem., Vol. 29 (1957), P. 1702-1706.

Google Scholar

[5] T. Ozawa: J. Therm. Anal., Vol. 2 (1970), 2: P. 301-324.

Google Scholar

[6] Wu Xiaoqing, Li Jia lu, Kang Zhuang and Wu Shi zhen: J. Solid Rocket Technol (china), Vol. 30(2007), P. 264-268.

Google Scholar

[7] L. Calabrese, A. Valenza: Eur. Polym. J., Vol. 39 (2003) p.1355–1363.

Google Scholar

[8] Crane LW, Dynes PJ and Kaelble DH. J: Polym. Sci. Polym. Lett. Ed, Vol. 11(1973) p.533–573.

Google Scholar