Study on Enhancement Adsorption of Pipemidic Acid from Aqueous Solution by Using an Amino Group Modified Hypercrosslinked Polymeric Adsorbents

Article Preview

Abstract:

In the present study, an amino group modified hypercrosslinked polymeric adsorbent RDM-200 was prepared and its ability to adsorb pipemidic acid from aqueous solution was tested by using Amberlite XAD-4 as a comparison. Pipemidic acid adsorption isotherm onto RDM-200 is well described by the Freundlich model. The RDM-200 adsorption capacity for PPA was about 510.5 mg/g at 293 K, exhibited larger uptake and stronger affinity of pipemidic acid than XAD-4. The adsorption thermodynamic parameters were calculated and the adsorption was an exothermic, favorable, and more ordered process. The RDM-200 spontaneously adsorbs pipemidic acid mainly by both entropy change and enthalpy change. The RDM-200 exhibited excellent adsorption ability over the pH range 6-10, NaCl showed the positive effect.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 468-471)

Pages:

1239-1242

Citation:

Online since:

February 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] E.K. Efthimiadou, Y. Sanakis, N. Katsaros, A. Karaliota, G. Psomas, Transition metal complexes with the quinolone antibacterial agent pipemidic acid: Synthesis, characterization and biological activity, Polyhedron. 26 (2007) 1148-1158.

DOI: 10.1016/j.poly.2006.10.017

Google Scholar

[2] J.L. Martinez, Antibiotics and Antibiotic Resistance Genes in Natural Environments, Sci. 321 (2008) 365-367.

Google Scholar

[3] W.H. Tao, A.M. Li, C. Long, H.M. Qian, D.J. Xu, J. Chen, Adsorption of 5-sodiosulfoisophthalic acids from aqueous solution onto poly (2-vinylpyridine) resin, J. Hazard. Mater. 175 (2010) 111-116.

DOI: 10.1016/j.jhazmat.2009.09.135

Google Scholar

[4] M. Greluk, Z. Hubicki, Kinetics, isotherm and thermodynamic studies of Reactive Black 5 removal by acid acrylic resins, Chem. Eng. J. 162 (2010) 919-926.

DOI: 10.1016/j.cej.2010.06.043

Google Scholar

[5] P.A. Gauden, A.P. Terzyk, P. Kowalczyk, Some remarks on the calculation of the pore size distribution function of activated carbons, J. Colloid Interface Sci. 300 (2006) 453-474.

DOI: 10.1016/j.jcis.2006.04.017

Google Scholar

[6] A. Turner, M.C. Rawling, The influence of salting out on the sorption of neutral organic compounds in estuaries, Water Res. 35 (2001) 4397-4389.

DOI: 10.1016/s0043-1354(01)00163-4

Google Scholar