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Solubility Product of MoC with NaCl Type Cubic Crystal Structure in Iron
Abstract:
In this paper, firstly, the equilibrium solubility product formula of MoC with NaCl type cubic crystal structure in ferrite has been deduced by thermodynamic method, according to the free energy change of molybdenum and carbon dissolved in ferrite and the formation energy of MoC. On the basis of deducing activity coefficients of Mo in iron, the solubility product formula of MoC in austenite has been obtained according to the relationship of solubility product of MoC in austenite and ferrite. Finally, the solubility products for MoC and NbC in iron are compared. The solubility product formulae of MoC deduced would play an important role in related theoretical research and practical production.
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281-285
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February 2012
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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