Preparation and Impact Properties of Epoxy/ Epoxidized Palm Oil Blend Glass Fiber Reinforced Composite Systems

Article Preview

Abstract:

Green thermosetting resins are were prepared using Epoxidizided palm oil (EPO) and epoxy based petroleum. The polymer resins were cured through amine system with the addition of various percentage of imidazole catalyst (5, 10, 25 and 30%). The evaluation for thermal due to high cross link densities blend samples toward heat. All the blend samples presented thermoset characteristics that was dependent upon the quantity of catalyst. As expected, the Tg decreased as the amount of imidazole increased.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 482-484)

Pages:

2400-2404

Citation:

Online since:

February 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Garima Tripathi, Deepak Srivastava, Studies on the physic-mechanical and thermal characteristics of blends of DGEBA epoxy, 3,4 epoxy cyclohexylmethyl, 3, 4'-epoxycylohexane carboxylate and carboxyl terminated butadiene co-acrylonitrile (CTBN), J. Mater. Sci. Eng. A. 496(2008), 483-493

DOI: 10.1016/j.msea.2008.06.035

Google Scholar

[2] Fanica Mutata, Nita Tudorachi, Dan Rosu, Curing and thermal behaviour of resin matric for composites based on epoxidized soybean oil/ diglycidyl ether of bisphenol A, Composites: Part B 42(2011) 1803-1812.

DOI: 10.1016/j.compositesb.2011.07.003

Google Scholar

[3] E. Annelise, Gerbase, L. Cesar, Petzhold, O. Ana Paula Costa, Dynamic mechanical and thermal behaviour of epoxy resins based soybean Oil, JAOCS, 79(2002), 8.

DOI: 10.1007/s11746-002-0561-z

Google Scholar

[4] W.D. Wan Rosli, R.N. Kumar, S. Mek Zah, M. Mohd Hilmi., UV radiation curing of epoxidized palm oil-cycloaliphatic diepoxide system induced by cationic photoinitiators for surface coatings, J. Eur. Polym. 39(2003)593-600.

DOI: 10.1016/s0014-3057(02)00241-0

Google Scholar

[5] F.L. Jin, S.J. Park, Impact strength improvement of epoxy resins reinforced with a biodegradable polymer, Mater. Sci. Eng. A, 478 (2008), 402-405.

DOI: 10.1016/j.msea.2007.05.053

Google Scholar

[6] S.G. Tan, W.S. Chow, Thermal properties, fracture toughness and water absorption of epoxy-palm oil blends, Polymer Plast. Tech. Eng. 49(2010), 900-907.

DOI: 10.1080/03602551003682042

Google Scholar

[7] A. Zlatanic, C. Lava, W. Zhang, Z.S. Petrovic, Effect of structure on properties of polyols and Polyurethanes based on different vegetable oil, J. Polym. Sci. Part B: Polym. Phys. 42(2004) 809-819.

DOI: 10.1002/polb.10737

Google Scholar

[8] C.R. Wold, M.D. Soucek, Viscoelastic and thermal properties of linseed oil-based creamer coatings, J. Macromol. Chem. Phys. 201(2000)382-392.

DOI: 10.1002/(sici)1521-3935(20000201)201:3<382::aid-macp382>3.0.co;2-9

Google Scholar

[9] S. G. Tan, W. S. Chow, Curing characteristics and thermal properties of epoxidized soybean oil based thermosetting resin, J. Am. Oil Chem. Soc. (2010).

DOI: 10.1007/s11746-010-1748-x

Google Scholar

[10] J. Zhu, A. Garg, K. Mekhissi, K. Chandrashekhara, V. Flanigan, S. Kapila, in., Proceedings of the 47th International SAMPE Symposium, 47(2002), 1209.

Google Scholar

[11] Suhreta Husic, Ivan Javni, S. Zoran Petrovic, Thermal and mechanical properties of glass reinforced soy-based polyurethane composites, J. Comp. Sci. Tech. 65 (2005)19-25.

DOI: 10.1016/j.compscitech.2004.05.020

Google Scholar

[12] J. Karger Kocris, K. Friedrich: submitted to Journal of Composite Science and Technology (1993)

Google Scholar

[13] A. Ozturk, C. Kaynak and T. Tincer: submitted to Journal of European Polymer, (2001)

Google Scholar

[14] P. Richard Wool., Xiuzhi Susan Sun, Bio-based polymers and composites, third ed., United Kingdom, 2005.

Google Scholar