Effect of Methyl Methacrylate Content in Carbon Black Filled Natural Rubber Compounds

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Natural rubber-grafted-poly(methyl methacrylate) containing 30 and 50 percent of methyl methacrylate (MMA) monomer per 100 parts by weight of the dry rubber content denoted as NR-g-PMMA 30 and NR-g-PMMA 50, respectively were prepared via emulsion polymerisation technique. The occurrences of graft copolymerisation of PMMA onto NR were confirmed by proton Nuclear Magnetic Resonance (1H NMR) and Fourier Transform Infrared (FTIR) following purifications. The reinforcement of rubber by fillers is of great practical and technical importance. Thus, these fillers are added to rubber formulations to optimize the properties to meet a given application or set of performance parameters. In this study, the effect of carbon black in NR-g-PMMA 30 and NR-g-PMMA 50 rubber compounds were evaluated. Our results demonstrated that tensile strength, elongation at break and compression set reduced, while the hardness and solvent resistance increased in the presence of carbon black filler in comparison to the unfilled compound.

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April 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.Subramaniam, Natural Rubber, in: Robert F.Ohm (Eds.), The Vanderbilt Rubber Handbook, 13th ed., R.T. Vanderbilt Company, Inc., 1990, pp.41-42

Google Scholar

[2] Anon. Megapoly – Asiatic Makes the Grade. Rubber Development, A Journal of the Malaysian Rubber Research and Development Board.. 41(1) (1988) 21-22.

Google Scholar

[3] Anon. Heveaplus MG, Rubber Development, A Journal of the Malaysian Rubber Research and Development Board. 24(4) (1971) 106-108.

Google Scholar

[4] A.R. Bevan, G.F. Bloomfield. Heveaplus MG in Adhesive –Part I. Natural Rubber Producers' Research Association (1963) 11-12.

Google Scholar

[5] R.N. Muthurajah. The Commercial Preparation of Methyl Methacrylate Graft Rubbers (Heveaplus MG49 and Heveaplus MG30). Planters Bulletin 74 (1964) 131-143.

Google Scholar

[6] E. Kalkornsurapranee, K. Sahakaro, A.Kaesaman, C.nakason. Influence of Reaction Volume on the Properties of Natural Rubber-grafted-Methyl Methacrylate. J. Elastomer and Plastics 00 (2009) 1-17.

DOI: 10.1177/0095244309345410

Google Scholar

[7] S.H.C. Man, A.S. Hashim, H.Md. Akil. Properties of Styrene-Methyl Methacrylate Grafted DPNR Latex at Different Monomer Concentrations. J. Applied Poly. Sc. 109 (2008) 9-15.

DOI: 10.1002/app.28047

Google Scholar

[8] D.H. A.Ismawi. Performance of Recovered Carbon Black from Waste Tyres in Rubber Compound. Malaysian Rubber Technology Developments 10 (2010) 31-35.

Google Scholar

[9] A.Mostafa, A.Abouel-Kasem, M.R. Bayoumi, M.G.El-Sebaie. Effect of Carbon Black Loading on the Swelling and Compression Set Behavior of SBR and NBR Rubber Compounds. Materials and Design. 30 (2009) 1561-1568.

DOI: 10.1016/j.matdes.2008.07.043

Google Scholar

[10] Barton, AFM. Handbook of Solubility Parameters and Other Cohesion Parameters, second ed., CRC Press, 1991.

Google Scholar

[11] H.A. Rahman. Morphology and Properties of Blends of NR and ENR. A Master's Thesis. 1990.

Google Scholar