The Formation Process of Black Trivalent Chromium Conversion Coating on Zn Electrodeposit

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Abstract:

A black trivalent chromium conversion coating (CCC) was obtained on Zn deposit in chromium trichloride solution at 55 °C. The formation process of trivalent CCC on Zn deposit were thoroughly investigated by using X-ray fluorescence spectrometer and X-ray photoelectron spectroscopy in combination with atomic force microscopy surface analysis. The trivalent CCC on Zn deposit is consisted of Zn, Cr, O, Ni, Co, P and N elements, with visible micro-cracks on the film’s surface. The growth rate, the surface color and the morphology of this conversion coating vary with the dipping time.

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Advanced Materials Research (Volumes 503-504)

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676-679

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April 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] N. Zaki, Trivalent Chrome Conversion Coating for Zinc and Zinc Alloys, Metal Finishing Vol. 100 (2002), pp.492-501.

DOI: 10.1016/s0026-0576(02)82052-9

Google Scholar

[2] H. Yu, B. Chen, X. Shi, X. Sun, B. Li, Investigation of the trivalent-chrome coating on 6063 aluminum alloy, Mater. Lett. Vol. 62 (2008), pp.2828-2831.

DOI: 10.1016/j.matlet.2008.01.056

Google Scholar

[3] K.W. Cho, R.V. Shankar, H.S. Kwon, Microstructure and electrochemical characterization of trivalent chromium based conversion coating on zinc, Electrochim. Acta Vol. 52 (2007), pp.4449-4456.

DOI: 10.1016/j.electacta.2006.12.032

Google Scholar

[4] B. Da Fonte Jr., Trivalent chromium passivate solution and process, U.S. Patent 4,359,345. (1982)

Google Scholar

[5] M.P. Gigandet, J. Faucheu, M. Tachez, Formation of black chromate conversion coatings on pure and Zinc alloy electrolytic deposits: role of the main constituents, Surface and Coatings Technology Vol. 89 (1997), pp.285-291.

DOI: 10.1016/s0257-8972(96)03013-7

Google Scholar

[6] Z.L. Long, Y.C. Zhou, L. Xiao, Characterization of black chromate conversion coating on the electrodeposited zinc–iron alloy, Appl. Surf. Sci. Vol. 218 (2003), pp.123-136.

DOI: 10.1016/s0169-4332(03)00572-5

Google Scholar

[7] W. Chen, C. Bai, C. Liu, C. Lin, M. Ger, The effect of chromic sulfate concentration and immersion time on the structures and anticorrosive performance of the Cr(III) conversion coatings on aluminum alloys, Appl. Surf. Sci. Vol. 256 (2010), pp.4924-4929.

DOI: 10.1016/j.apsusc.2010.03.003

Google Scholar