Luminescence Properties of Zn2Si1+xO4+2x: Mn2+ in UV and VUV Region

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Abstract:

Phosphors Zn2Si1+xO4+2x: Mn2+(0x0.5) were synthesized through sol-gel process and their photoluminescence in UV and VUV region were investigated. At 254 nm excitation, the phosphor gives intense green emission (527 nm) and the luminescence intensity was enhanced with the increasing of x. At 147 nm excitation, the optimum luminescence intensity occurred at x = 0.1 and the absorption of host became blue shift slightly, which could be related with the absorption of excess SiO2. The sample Zn2Si1.1O4.2 had the highest emission intensity and it is 40% higher than that of Zn2SiO4:Mn2+.

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April 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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