Preparation and Electrochemical Performances of Li4Ti5O12 as Anode Material

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Abstract:

Spinel Li4Ti5O12 was prepared by a solution method. The structure and morphology of the samples were characterized by X-ray diffraction, scanning electron microscopy. The electrochemical performance was investigated by initial charge-discharge at different rate. The results revealed that the crystallinity of Li4Ti5O12 was well, the Li4Ti5O12 prepared by solution method had a relatively smaller particle size and homogeneous morphology. It delivered a discharge capacity 178.59 mAh•g−1 for the Li4Ti5O12 at the 0.2C discharge to 1V. The reversible capacity 141.98mAh•g−1 could be achieved at the 5C . Li4Ti5O12 prepared by a solution method showed good rate performance.

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Advanced Materials Research (Volumes 512-515)

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1976-1979

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May 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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