Determination of Nonylphenol and Octylphenol in Seawater Samples Using Solid-Phase Microextraction Procedures Coupled to Gas Chromatography–Mass Spectrometry

Xian Yin Ping; Hui Sheng Zhuang

doi:10.4028/www.scientific.net/AMR.518-523.1496

Paper Titles

Assessment of Greenhouse Gas (GHG) Emissions of Polylactic Acid (PLA)/Starch and Polyethylene Terephthalate (PET) Trays
p.1468

Atmospheric Environmental Monitoring System Based on Wireless Sensor Network
p.1475

Characterization of PM2.5- and PM10-Bound Polycyclic Aromatic Hydrocarbons in Urban and Rural Areas in Beijing during the Winter
p.1479

Comparison of CO₂ Net Exchange between Different Plant Communities in Typical Steppe of Inner Mongolia Plateau
p.1492

Determination of Nonylphenol and Octylphenol in Seawater Samples Using Solid-Phase Microextraction Procedures Coupled to Gas Chromatography–Mass Spectrometry
p.1496

Determination of PAHs in River Water Using Bamboo Charcoal as a Solid-Phase Extraction Adsorbent by Synchronous Fluorescence Spectrometry
p.1501

Determination of Total Hardness in Drinking Water by Microscale Chemistry Experiment
p.1506

Development and Application of Continuous Atmospheric Heavy Metals Monitoring System Based on X-Ray Fluorescence
p.1510

Distribution, Sources and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in Water of the Provincial Control Section River, Longyan
p.1516

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 518-523Determination of Nonylphenol and Octylphenol in...

Determination of Nonylphenol and Octylphenol in Seawater Samples Using Solid-Phase Microextraction Procedures Coupled to Gas Chromatography–Mass Spectrometry

Abstract:

The solid-phase microextraction (SPME) technique with on-fiber derivatization coupled to gas chromatography–mass spectrometry was evaluated for the analysis of technical nonylphenol (NP) and octylphenol (OP). The optimization of operating conditions influencing the performances of SPME and derivatization were studied in detail. The optimised method was linear over the range studied and showed good level of precision, with a RSD lower than 10% and detection limits at and 0.003 μgL⁻¹ for OP and 0.032μgL⁻¹ for NP, respectively. The results obtained from different seawater samples revealed the presence of the target compounds, at levels ranging between 0.034 and 0.186 μgL⁻¹.

You might also be interested in these eBooks

Advances in Environmental Science and Engineering

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 518-523)

Pages:

1496-1500

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.518-523.1496

Citation:

Cite this paper

Online since:

May 2012

Authors:

Xian Yin Ping, Hui Sheng Zhuang

Keywords:

Gas Chromatography (GC), Nonylphenol, Solid-Phase Microextraction

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] R. Renner: Environ. Sci. Technol Vol. 31 (1997), p. 316A.

Google Scholar

[2] A. Díaz, F. Ventura and M.T. Galceran: J. Chromatogr. A Vol. 963 (2002), p.159.

Google Scholar

[3] G.G. Ying: Environ. Int. Vol. 32 (2006), p.417.

Google Scholar

[4] S.S. Madsen, S. Skovbolling, C. Nielsen and B. Korsgaard: Aquat. Toxicol. Vol. 68 (2004), p.109.

Google Scholar

[5] EU Cement Directive: Directive 2003/53/EC of the European Parliament and of the Council, Official Journal of the European Union, Luxembourg, 2003.

Google Scholar

[6] Z. Xie, J. Selzer, R. Ebinghaus, A. Caba and W. Ruck: Anal. Chim. Acta Vol. 565 (2006), p.198.

Google Scholar

[7] C.Y. Cheng, C.Y. Wu, C.H. Wang and W.H. Ding: Chemosphere Vol. 65 (2006), p.2275.

Google Scholar

[8] X. Peng, Z. Wang, C. Yang, F. Chen and B. Mai: J. Chromatogr. A Vol. 1116 (2006), p.51.

Google Scholar

[9] C. Basheer, A. Parthiban, A. Jayaraman, H.K. Lee and S. Valiyaveettil: J. Chromatogr. A Vol. 1087 (2005), p.274.

Google Scholar

[10] J. Pawliszyn: Applications of Solid Phase Microextraction, Royal Society of Chemistry, Cambridge (1999).

Google Scholar

[11] J.A. Koziel and J. Pawliszyn: J. Air Waste Manage. Assoc Vol. 51 (2001), p.173.

Google Scholar

[12] B. Chen, J.C. Duan, B.X. Mai et al.: Chemosphere Vol. 63（2005）, pp.652-661.

Google Scholar