Synthesis, Structure and Photoluminescence of a Potential Luminescent Material of Mn(II) Coordination Polymer

Abstract:

A new coordination polymer [Mn₃(IP)(4,4'-obb)3]_n (1) (4,4'-obb = 4,4'-Oxybisbenzoic acid, IP = 1H-imidazo[4,5-f][1,10]-phenanthroline) was synthesized and characterized by IR, elemental analysis and X-ray diffraction. Single-crystal X-ray analyses revealed that the compound demonstrates 1D structure in which the Mn₂₊ centers are connected via 4,4'-obb anions into 1D chain, the chains are further connected via hydrogen - bonding and π ••• π interactions. In addition, the photoluminescence for compound 1 is also investigated in the solid state at room temperature.

• Periodical: Advanced Materials Research (Volume 528)
• Pages: 206-209
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.528.206
• Online since: June 2012
• Authors: Xiu Ling Zhang, Kai Cheng, Yu Lan Song
• Keywords: Coordination Polymer, Crystal Structure, Luminescent Properties, Synthesis

References

[1] W.L. Liu, L.H. Ye, X.F. Liu, L.L. Yuan, J.X. Jiang, C.G. Yan, Hydrothermal syntheses, structures and luminescent properties of d10 metal–organic frameworks based on rigid 3, 3', 5, 5'-azobenzenetetracarboxylic acid, Cryst. Eng. Comm. 10 (2008).

DOI: 10.1039/b806360e

[2] C.J. Doonan, W. Morris, H. Furukawa, O.M. Yaghi, Isoreticular metalation of metal-organic frameworks, J. Am. Chem. Soc. 131 (2009) 9492-9493.

DOI: 10.1021/ja903251e

[3] J.P. Zhang, Y.Y. Lin, X.C. Huang, X.M. Chen, Copper (I) 1, 2, 4-tTriazolates and related complexes: studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties, J. Am. Chem. Soc. 127 (2005) 5495-5506.

DOI: 10.1021/ja042222t

[4] J.B. Lin, J.P. Zhang, X.M. Chen, Nonclassical active site for enhanced gas sorption in porous coordination polymer, J. Am. Chem. Soc. 132 (2010) 6654-6656.

DOI: 10.1021/ja1009635

[5] C.C. Ji, L.F. Huang, J. Li, H.G. Zheng, Y.Z. Li, Z.J. Guo, Solvothermal syntheses, structures, and physical properties of four new coordination compounds constructed from a bent dicarboxylate ligand, Dalton Trans. 39 (2010) 8240-8247.

DOI: 10.1039/c0dt00352b

[6] Bruker, SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA (2007).

[7] Bruker, SADABS, Bruker AXS Inc., Madison, Wisconsin, USA (2001).

[8] A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori, R. Spagna, SIR97: a new tool for crystal structure determination and refinement, J. Appl. Cryst. 32 (1999) 115-119.

DOI: 10.1107/s0021889898007717

[9] G.M. Sheldrick, A short history of SHELX, Acta Cryst. A64 (2008) 112-122.

[10] C.L. Chen, C.Y. Su, Y.P. Cai, H.X. Zhang, A.W. Xu, B.S. Kang, H.C. Zur Loye, Multidimensional frameworks assembled from silver(I) coordination polymers containing flexible bis(thioquinolyl) ligands: role of the intra- and intermolecular aromatic stacking interactions, Inorg. Chem. 42 (2003).

DOI: 10.1021/ic0341035

[11] S.J. Wang, S.S. Xiong, L.X. Song, Z.Y. Wang, Influence of co-ligands and solvents on the packing and photoluminescence of three related MnII metal–organic frameworks, Cryst. Eng. Comm. 11 (2009) 896-901.

DOI: 10.1039/b817418k