The Effects of Selenization Temperature on the Properties of CIGS Thin Film Prepared by Cu-In-Ga-Se Precursors

Article Preview

Abstract:

CIGS thin films were prepared by selenization of Cu-In-Ga-Se precursors, as a new method, the effects of selenization temperature on the properties of CIGS thin films were studied. First, Cu-In-Ga-Se precursors were deposited onto Mo-coated soda lime glass by evaporation and sputtering method. Then, precursors were selenized at various temperatures in N2 atmosphere for 120 min to form CIGS thin films. The degree of reaction and morphology of films as a function of selenization temperature were analyzed. By means of field emission scanning electron microscope (SEM) and X-ray diffraction (XRD), it was found that CIGS thin films selenized at 450°C exhibit chalcopyrite phase with preferred orientation along the (112) plane.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

214-218

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Niki, M. Contreras, I. Repins, M. Powalla, K. Kushiya, S. Ishizuka, K. Matsubara, CIGS absorbers and processes, Prog. Photovolt.: Res. Appl. 18 (2010) 453–466.

DOI: 10.1002/pip.969

Google Scholar

[2] R. Caballer, C. Guillen, Optical and electrical properties of Cu(In1-xGax)Se2 thin films obtained by selenization of sequentially evaporated metallic layers, Thin Solid Films 431 (2003) 200-204.

DOI: 10.1016/s0040-6090(03)00212-8

Google Scholar

[3] M.A. Contreras, K. Ramanathan, J. AbuShama, F. Hasoon, D.L. Young, B. Egaas and R. Noufi, Diode characteristics in state-of-the-art ZnO/CdS/Cu(In1−xGax)Se2 Solar Cells, Prog. Photovolt.: Res. Appl. 13 (2005) 209–216.

DOI: 10.1002/pip.626

Google Scholar

[4] M.A. Contreras, B. Egaas, K. Ramanathan, J. Hiltner, A. Swartzlander, F. Hasoon and R. Noufi, Progress toward 20% efficiency in Cu(In,Ga)Se2 polycrystalline thin-film solar cells, Prog. Photovolt.: Res. Appl. 7 (1999) 311–316.

DOI: 10.1002/(sici)1099-159x(199907/08)7:4<311::aid-pip274>3.0.co;2-g

Google Scholar

[5] S.D. Kim, H.J. Kim, K.H. Yoon, J. Song, Effect of selenization pressure on CuInSe2 thin films selenized using co-sputtered Cu-In precursors, Sol. Energy Mater. Sol. Cells 62 (2000) 357-368.

DOI: 10.1016/s0927-0248(99)00157-9

Google Scholar

[6] H.K. Song, J.K. Jeong, H.J. Kim, S.K, Kim, K.H, Yoon, Fabrication of Cu(In1−xGax)Se2 thin film solar cells by sputtering and selenization process, Thin Solid Films 435 (2003) 186-192.

DOI: 10.1016/s0040-6090(03)00350-x

Google Scholar

[7] C.Y. Su, W.H. Ho, H.C. Lin, C.Y. Nieh, S.C. Liang, The effects of the morphology on the CIGS thin films prepared by CuInGa single precursor, Sol. Energy Mater. Sol. Cells 95 (2011) 261–263.

DOI: 10.1016/j.solmat.2010.04.072

Google Scholar

[8] G.S. Chen, J.C. Yang, Y.C. Chan, L.C. Yang, Welson Huang, Another route to fabricate single-phase chalcogenides by post-selenization of Cu–In–Ga precursors sputter deposited from a single ternary target, Sol. Energy Mater. Sol. Cells 93 (2009) 1351–1355.

DOI: 10.1016/j.solmat.2009.02.014

Google Scholar

[9] F.D. Jiang, J.Y. Feng, Effect of temperature on selenization process of metallic Cu-In alloy precursors, Thin Solid Films 515 (2006) 1950-1955.

DOI: 10.1016/j.tsf.2006.07.154

Google Scholar

[10] R. Caballero, C. Maffiotte, C. Guillen, Preparation and characterization of CuIn1−xGaxSe2 thin films obtained by sequential evaporations and different selenization processes, Thin Solid Films 474 (2005) 70-76.

DOI: 10.1016/j.tsf.2004.08.010

Google Scholar