Influence on Electrochemical Performance of LiMnPO4 by Y Doping Using Low Combustion Synthesis Method

Article Preview

Abstract:

The olivine LiMnPO4 used as cathode materials was synthesized by the low combustion synthesis method, and modified by doping Y. Testing of X-ray diffraction (XRD),scanning electron microscopy (SEM),charge-discharge measurements was carried out for LiMnPO4/C cathode materials and the modified materials. The synthesized materials doping by Y exhibited standard olivine structure, nano-sized particles, discharge capacity of 122.9mAh.g-1 and good cycling performance. These results indicated that less Y doping could improve electrochemical kinetics of lithium ion extraction/insertion and significantly enhanced electrochemical activity.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

411-414

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. K. Padhi, K. S. Nanjundaswamy, and J. B. Goodenough: J. Electrochem. Soc. Vol 144(1997), pp.1188-1194.

Google Scholar

[2] A. Yamada, S. C. Chung, and K. Hinokuna: J. Electrochem. Soc. Vol 148(2001), pp.224-229.

Google Scholar

[3] A. Yamada, M. Hosoya S.C. Chung: J. Power Sources. Vol 119(2003), pp.119-232.

Google Scholar

[4] C. Delacourt, P. Poizot, M. Morcrette, and C. Masquelier: Chem. Mater. Vol 16(2004), pp.93-99.

Google Scholar

[5] T. Drezen, N.H. Kwon, et al.: J. Power Sources. Vol 174(2007), pp.949-953.

Google Scholar

[6] N.H. Kwon,T. Drezen.I. Exnar,I. Teerlinck: Elctrochem. Solid-State Lett. Vol 9(2006), pp.277-280.

Google Scholar

[7] J. Chandradass. and Ki Hyeon Kim: Advanced Powder Technology. Vol 21(2010), pp.100-105.

Google Scholar

[8] K. Tahmasebi, M.H. Paydar: Materials Chemistry and Physics, Vol 109(2008), pp.156-163.

Google Scholar

[9] Belharouak, I., C. Johnson and K. Amine: Electrochemistry Communications. Vol 10(2005), pp.983-988.

Google Scholar

[10] T. Nakamura, Y. Shima, H. Matsui, et al.: J. Electrochem. Soc. Vol 157(2010), pp.544-549.

Google Scholar