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Influence on Electrochemical Performance of LiMnPO4 by Y Doping Using Low Combustion Synthesis Method
Abstract:
The olivine LiMnPO4 used as cathode materials was synthesized by the low combustion synthesis method, and modified by doping Y. Testing of X-ray diffraction (XRD),scanning electron microscopy (SEM),charge-discharge measurements was carried out for LiMnPO4/C cathode materials and the modified materials. The synthesized materials doping by Y exhibited standard olivine structure, nano-sized particles, discharge capacity of 122.9mAh.g-1 and good cycling performance. These results indicated that less Y doping could improve electrochemical kinetics of lithium ion extraction/insertion and significantly enhanced electrochemical activity.
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411-414
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June 2012
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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