Properties of High Solid Content UV Curable Waterborne Polyurethane Dispersions with Different C=C Content

Yong Bin Jiu; Xin Miao Zeng; Jun Hui Ji; Yu Zhai; Lian Cai Wang

doi:10.4028/www.scientific.net/AMR.535-537.1158

Paper Titles

Study and Application on Layered Polymer Injection with Concentric String
p.1135

Effect of Hyperbranched Polymer on Crystallization Kinetics of Isotactic Polypropylene
p.1142

Effect of Process Parameters on Jet Length in Electrospraying of Thermoplastic Polymer
p.1146

Preparation of Rigid Flame Retardancy Polyurethane Foam Material with Difficult Combusted Degree
p.1151

Properties of High Solid Content UV Curable Waterborne Polyurethane Dispersions with Different C=C Content
p.1158

The Reaserch of Displacement Oil of the Polymer System with the Low Interfacial Tension Conditions
p.1163

Evaluation of the Thermal Stabilization Effect of Maleic Anhydride Derivatives on Polyvinyl Chloride
p.1167

Synthesis of Hydrophobic Modified Polyacrylamide Functional Materials in Supercritical CO₂
p.1171

Discussion upon the Draft Ratio Affecting PEN-PPS Filaments
p.1176

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 535-537Properties of High Solid Content UV Curable...

Properties of High Solid Content UV Curable Waterborne Polyurethane Dispersions with Different C=C Content

Abstract:

Ultraviolet (UV) curable waterborne polyurethane(WPU) dispersions based on isophorone diisocyanate(IPDI), polypropylene glycol(PPG), dimethylolproprionic acid(DMPA) and pentaerythritol triacrylate(PETA) were prepared by the conventional method of anionic aqueous polyurethane dispersions. The structure of the ultraviolet (UV) curable WPU dispersions was studied by FT-IR. Stability, dispersion particle size and zeta-potential of the WPU dispersions were characterized. Effect of temperature on viscosity of the dispersions with different C=C content was also investigated. Results showed that all UV curable WPU dispersions had high solid content (48wt%) and showed remarkable mechanical stability. The viscosity of the dispersions decreased with temperature increasing from 20°C to 60°C. When C=C content varied from 0 to 1.05meq/g, the dispersion particle size was under 300nm, zeta potentials were less than -48.9mV.